Matches in SemOpenAlex for { <https://semopenalex.org/work/W4285223355> ?p ?o ?g. }
- W4285223355 endingPage "424" @default.
- W4285223355 startingPage "413" @default.
- W4285223355 abstract "Mechanochemistry has been extended to various polymer syntheses to achieve efficiency, greenness, and new products. However, many fundamental polymerization reactions have not been explored, although anionic polymerization of vinyl compounds has been pursued under mechanochemical conditions. Two solid monomers, 4-biphenyl methacrylate and 4-vinyl biphenyl, representing methacrylate and styrenic classes, respectively, were reacted with secondary butyl lithium under high-speed ball-milling. The alkyl-anion-promoted polymerization process was established by excluding radical initiation and producing the expected polymers with good efficiency. However, the generally expected features of anionic polymerization, such as molecular weight control and narrow dispersity, were not observed. Analysis of the milling parameters, reaction monitoring, and microstructural analysis revealed that the mechanism of the mechanochemical process differs from that of conventional anionic polymerizations. The mechanical force fractured the newly formed polymer chains via anionic initiation and generated macroradicals, which participated in the polymerization process. The anionic process governs the initiation step and the radical process becomes dominant during the propagation step." @default.
- W4285223355 created "2022-07-14" @default.
- W4285223355 creator A5021302838 @default.
- W4285223355 creator A5034945169 @default.
- W4285223355 creator A5036465401 @default.
- W4285223355 creator A5079168057 @default.
- W4285223355 creator A5090197814 @default.
- W4285223355 date "2023-01-01" @default.
- W4285223355 modified "2023-10-01" @default.
- W4285223355 title "Mechanochemical solid-state vinyl polymerization with anionic initiator" @default.
- W4285223355 cites W1963763088 @default.
- W4285223355 cites W1968371747 @default.
- W4285223355 cites W1968686690 @default.
- W4285223355 cites W1977032297 @default.
- W4285223355 cites W1981841209 @default.
- W4285223355 cites W1999034326 @default.
- W4285223355 cites W2017287052 @default.
- W4285223355 cites W2017864217 @default.
- W4285223355 cites W2020756233 @default.
- W4285223355 cites W2021443738 @default.
- W4285223355 cites W2022752151 @default.
- W4285223355 cites W2030163283 @default.
- W4285223355 cites W2033586545 @default.
- W4285223355 cites W2035780955 @default.
- W4285223355 cites W2041141361 @default.
- W4285223355 cites W2051980182 @default.
- W4285223355 cites W2063731921 @default.
- W4285223355 cites W2091205209 @default.
- W4285223355 cites W2092236107 @default.
- W4285223355 cites W2093881231 @default.
- W4285223355 cites W2159582789 @default.
- W4285223355 cites W2167564712 @default.
- W4285223355 cites W2225648132 @default.
- W4285223355 cites W2334118835 @default.
- W4285223355 cites W2346538334 @default.
- W4285223355 cites W2415904663 @default.
- W4285223355 cites W2472720147 @default.
- W4285223355 cites W2565783413 @default.
- W4285223355 cites W2610874247 @default.
- W4285223355 cites W2643524967 @default.
- W4285223355 cites W2726768352 @default.
- W4285223355 cites W2754736905 @default.
- W4285223355 cites W2778428298 @default.
- W4285223355 cites W2888616955 @default.
- W4285223355 cites W2898937789 @default.
- W4285223355 cites W2904094881 @default.
- W4285223355 cites W2916376794 @default.
- W4285223355 cites W2942276602 @default.
- W4285223355 cites W2979798662 @default.
- W4285223355 cites W3010322587 @default.
- W4285223355 cites W3024984442 @default.
- W4285223355 cites W3083027390 @default.
- W4285223355 cites W3089025842 @default.
- W4285223355 cites W3092956341 @default.
- W4285223355 cites W3186130209 @default.
- W4285223355 cites W3208485959 @default.
- W4285223355 cites W3214405978 @default.
- W4285223355 cites W4220944880 @default.
- W4285223355 cites W4244837715 @default.
- W4285223355 cites W4245501032 @default.
- W4285223355 cites W4296126704 @default.
- W4285223355 doi "https://doi.org/10.1039/d2fd00080f" @default.
- W4285223355 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36124991" @default.
- W4285223355 hasPublicationYear "2023" @default.
- W4285223355 type Work @default.
- W4285223355 citedByCount "4" @default.
- W4285223355 countsByYear W42852233552022 @default.
- W4285223355 countsByYear W42852233552023 @default.
- W4285223355 crossrefType "journal-article" @default.
- W4285223355 hasAuthorship W4285223355A5021302838 @default.
- W4285223355 hasAuthorship W4285223355A5034945169 @default.
- W4285223355 hasAuthorship W4285223355A5036465401 @default.
- W4285223355 hasAuthorship W4285223355A5079168057 @default.
- W4285223355 hasAuthorship W4285223355A5090197814 @default.
- W4285223355 hasConcept C111998727 @default.
- W4285223355 hasConcept C11432220 @default.
- W4285223355 hasConcept C121120078 @default.
- W4285223355 hasConcept C127413603 @default.
- W4285223355 hasConcept C151286553 @default.
- W4285223355 hasConcept C159985019 @default.
- W4285223355 hasConcept C166940927 @default.
- W4285223355 hasConcept C167076587 @default.
- W4285223355 hasConcept C178790620 @default.
- W4285223355 hasConcept C185592680 @default.
- W4285223355 hasConcept C188027245 @default.
- W4285223355 hasConcept C192562407 @default.
- W4285223355 hasConcept C34594497 @default.
- W4285223355 hasConcept C42360764 @default.
- W4285223355 hasConcept C44228677 @default.
- W4285223355 hasConcept C48396125 @default.
- W4285223355 hasConcept C508816927 @default.
- W4285223355 hasConcept C521977710 @default.
- W4285223355 hasConcept C53856295 @default.
- W4285223355 hasConcept C79019126 @default.
- W4285223355 hasConcept C84687054 @default.
- W4285223355 hasConcept C89760097 @default.
- W4285223355 hasConceptScore W4285223355C111998727 @default.
- W4285223355 hasConceptScore W4285223355C11432220 @default.