FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4285248082> ?p ?o ?g. }

• W4285248082 endingPage "9158" @default.
• W4285248082 startingPage "9147" @default.
• W4285248082 abstract "To access the hitherto almost unknown class of clustered transition metal carbonyl cations, the trimetal dodecacarbonyls M3(CO)12 (M = Ru, Os) were reacted with the oxidant Ag+[WCA]-, but yielded the silver complexes [Ag{M3(CO)12}2]+[WCA]- (WCA = [Al(ORF)4]-, [F{Al(ORF)3}2]-; RF = -OC(CF3)3). Addition of further diiodine I2 to increase the redox potential led for M = Ru non-specifically to divalent mixed iodo-RuII-carbonyl cations. With [NO]+, even the N-O bond was cleaved and led to the butterfly carbonyl complex cation [Ru4N(CO)13]+ in low yield. Obviously, ionization of M3(CO)12 with retention of its pseudo-binary composition including only M and CO is difficult and the inorganic reagents did react non-innocently. Yet, the radical cation of the commercially available perhalogenated anthracene derivative 9,10-dichlorooctafluoroanthracene (anthraceneHal) is a straightforward accessible innocent deelectronator with a half-wave potential E1/2 of 1.42 V vs. Fc0/+. It deelectronates M3(CO)12 under a CO atmosphere and leads to the structurally characterized cluster salts [M3(CO)14]2+([WCA]-)2 including a linear M3 chain. The structural characterization as well as vibrational and NMR spectroscopies indicate the presence of three electronically independent sets of carbonyl ligands, which almost mimic M(CO)5, free CO and even [M(CO)6]2+ in one and the same cation." @default.
• W4285248082 created "2022-07-14" @default.
• W4285248082 creator A5017869996 @default.
• W4285248082 creator A5019698345 @default.
• W4285248082 creator A5035919046 @default.
• W4285248082 creator A5079554724 @default.
• W4285248082 creator A5083560305 @default.
• W4285248082 date "2022-01-01" @default.
• W4285248082 modified "2023-10-18" @default.
• W4285248082 title "Towards clustered carbonyl cations [M₃(CO)₁₄]²⁺ (M = Ru, Os): the need for innocent deelectronation" @default.
• W4285248082 cites W1144565994 @default.
• W4285248082 cites W1968955201 @default.
• W4285248082 cites W1978765368 @default.
• W4285248082 cites W1979758217 @default.
• W4285248082 cites W1982027396 @default.
• W4285248082 cites W1985548136 @default.
• W4285248082 cites W1991183652 @default.
• W4285248082 cites W1991644396 @default.
• W4285248082 cites W1997199877 @default.
• W4285248082 cites W2000640390 @default.
• W4285248082 cites W2001243564 @default.
• W4285248082 cites W2005061184 @default.
• W4285248082 cites W2009063105 @default.
• W4285248082 cites W2010073896 @default.
• W4285248082 cites W2013303071 @default.
• W4285248082 cites W2014559224 @default.
• W4285248082 cites W2018031098 @default.
• W4285248082 cites W2020624761 @default.
• W4285248082 cites W2023418543 @default.
• W4285248082 cites W2025402712 @default.
• W4285248082 cites W2028933599 @default.
• W4285248082 cites W2030281646 @default.
• W4285248082 cites W2030841140 @default.
• W4285248082 cites W2035975323 @default.
• W4285248082 cites W2036506911 @default.
• W4285248082 cites W2039524283 @default.
• W4285248082 cites W2039576759 @default.
• W4285248082 cites W2048951971 @default.
• W4285248082 cites W2054605309 @default.
• W4285248082 cites W2066492490 @default.
• W4285248082 cites W2069506033 @default.
• W4285248082 cites W2071783532 @default.
• W4285248082 cites W2072672419 @default.
• W4285248082 cites W2073456741 @default.
• W4285248082 cites W2078712305 @default.
• W4285248082 cites W2079028867 @default.
• W4285248082 cites W2081440341 @default.
• W4285248082 cites W2082035310 @default.
• W4285248082 cites W2084675752 @default.
• W4285248082 cites W2086819865 @default.
• W4285248082 cites W2088254513 @default.
• W4285248082 cites W2091208014 @default.
• W4285248082 cites W2092923411 @default.
• W4285248082 cites W2093539793 @default.
• W4285248082 cites W2095061599 @default.
• W4285248082 cites W2110267483 @default.
• W4285248082 cites W2118585686 @default.
• W4285248082 cites W2127421716 @default.
• W4285248082 cites W2135905922 @default.
• W4285248082 cites W2136865058 @default.
• W4285248082 cites W2156257115 @default.
• W4285248082 cites W2159867582 @default.
• W4285248082 cites W2163748451 @default.
• W4285248082 cites W2195543846 @default.
• W4285248082 cites W2233906098 @default.
• W4285248082 cites W2314122827 @default.
• W4285248082 cites W2319627834 @default.
• W4285248082 cites W2330412095 @default.
• W4285248082 cites W2330649728 @default.
• W4285248082 cites W2465659121 @default.
• W4285248082 cites W2474109913 @default.
• W4285248082 cites W2757230468 @default.
• W4285248082 cites W2766899396 @default.
• W4285248082 cites W2789978290 @default.
• W4285248082 cites W2893758139 @default.
• W4285248082 cites W2895405209 @default.
• W4285248082 cites W2908265108 @default.
• W4285248082 cites W2912253038 @default.
• W4285248082 cites W2951038815 @default.
• W4285248082 cites W3003153613 @default.
• W4285248082 cites W3004675425 @default.
• W4285248082 cites W3009039087 @default.
• W4285248082 cites W3012397535 @default.
• W4285248082 cites W3012790451 @default.
• W4285248082 cites W3032560617 @default.
• W4285248082 cites W3036003733 @default.
• W4285248082 cites W3085345383 @default.
• W4285248082 cites W3092143176 @default.
• W4285248082 cites W3096497273 @default.
• W4285248082 cites W3120783237 @default.
• W4285248082 cites W3127425582 @default.
• W4285248082 cites W3135712116 @default.
• W4285248082 cites W3136749317 @default.
• W4285248082 cites W3153886641 @default.
• W4285248082 cites W3200907444 @default.
• W4285248082 cites W4211264536 @default.
• W4285248082 cites W4238899971 @default.
• W4285248082 cites W4253081814 @default.

• next