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- W4285264904 abstract "The construction of novel molecules with unprecedented alignments of the constituent elements has revolutionized the field of functional materials. The arrangement of two or more planar subunits in a mutually perpendicular fashion is a frequently encountered approach to produce novel functional materials. Previous examples of such materials can be categorized into two well-investigated families: spiro-conjugated and dumbbell-shaped structures, wherein the two planes are aligned orthogonally via a single atom or an axis, respectively. This article describes a third family: reaction of [Pd(CN t Bu)2]3 with Sn3Me8 or Ge6Me12 afforded a Pd7Sn4 cluster and a Pd8Ge6 cluster that consist of two mutually bisecting perpendicular planes. In the Pd7Sn4 cluster, the two equivalent Pd5Sn2 planes share three palladium atoms that include a dihedral angle of 85.6°." @default.
- W4285264904 created "2022-07-14" @default.
- W4285264904 creator A5003500065 @default.
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- W4285264904 date "2022-01-01" @default.
- W4285264904 modified "2023-10-01" @default.
- W4285264904 title "Discrete palladium clusters that consist of two mutually bisecting perpendicular planes" @default.
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- W4285264904 doi "https://doi.org/10.1039/d2sc02302d" @default.
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