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• W4285272257 endingPage "124" @default.
• W4285272257 startingPage "79" @default.
• W4285272257 abstract "Globally escalating energy demands and environmental restrictions concerning the use of fossil fuels have stimulated extensive research in the area of sustainable, clean, low-cost, and above all environmentally benign energy sources. Aerobic respiration is the most important life process that relies on oxygen reduction reaction (ORR), where molecular oxygen is selectively reduced to water by the perfectly arranged tris-copper and bis-heme centers present in cytochrome c oxidase. This process leads to the release of energy, which is stored as ATP. Getting inspiration from nature, many scientists have designed different model systems that can be useful as alternative energy resources. This ORR also plays a pivotal role in the energy transformation process in alternative energy generation devices, such as metal-air batteries and fuel cells (FCs). ORR as a FC cathodic reaction is a key step that affects the efficiency of overall energy conversion. Catalysts play important roles in this process by improving the kinetics of these reactions. The kinetics of ORR at the cathode is a major factor for the performance of electrocatalysts. Low kinetic rates, high over-potential, and consequential energy loss are the bottlenecks, which must be prevented to make such devices commercially viable. Pt-based electrocatalysts are most efficient, although they offers limited scope of commercialization of FCs as it is scarce and costly. It is also reported that Pt still shows over-potentials of over 200 mV from the equilibrium reversible potentials. This has forced the scientific community to extensively research on developing alternative catalysts. Tetrapyrrolic ligands like porphyrin, phthalocyanine, and corrole-based systems are versatile and can very efficiently catalyze ORR when bound to metals like Fe, Co, and Cu. First row transition metallophthalocyanine (MPc) and metallocorroles are potential electrocatalysts for many reactions, and they may eventually be used as true alternatives to the precious metals currently in use. Regarding ORR, halogenated cobalt-corroles and iron-phthalocyanines can match the potentiality of an industry standard, platinum-based catalyst. In this chapter, we would like to focus on the progress that has been made in this field of metallocorrole and metallophthalocyanine for ORR activity." @default.
• W4285272257 created "2022-07-14" @default.
• W4285272257 creator A5022253382 @default.
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• W4285272257 creator A5056396186 @default.
• W4285272257 date "2022-01-01" @default.
• W4285272257 modified "2023-09-27" @default.
• W4285272257 title "Oxygen reduction reaction by metallocorroles and metallophthalocyanines" @default.
• W4285272257 cites W1168565912 @default.
• W4285272257 cites W1754067924 @default.
• W4285272257 cites W1964180619 @default.
• W4285272257 cites W1967312148 @default.
• W4285272257 cites W1972989663 @default.
• W4285272257 cites W1975355238 @default.
• W4285272257 cites W1978273949 @default.
• W4285272257 cites W1983568173 @default.
• W4285272257 cites W1984362112 @default.
• W4285272257 cites W1989715071 @default.
• W4285272257 cites W1992480871 @default.
• W4285272257 cites W1993904532 @default.
• W4285272257 cites W1994204270 @default.
• W4285272257 cites W1996946244 @default.
• W4285272257 cites W2000284586 @default.
• W4285272257 cites W2001413638 @default.
• W4285272257 cites W2009901571 @default.
• W4285272257 cites W2014266836 @default.
• W4285272257 cites W2016349291 @default.
• W4285272257 cites W2016982578 @default.
• W4285272257 cites W2020324351 @default.
• W4285272257 cites W2025483887 @default.
• W4285272257 cites W2028359667 @default.
• W4285272257 cites W2031302556 @default.
• W4285272257 cites W2035226216 @default.
• W4285272257 cites W2037096863 @default.
• W4285272257 cites W2040260467 @default.
• W4285272257 cites W2040399060 @default.
• W4285272257 cites W2042080918 @default.
• W4285272257 cites W2047743895 @default.
• W4285272257 cites W2048629281 @default.
• W4285272257 cites W2052280700 @default.
• W4285272257 cites W2057868487 @default.
• W4285272257 cites W2058965957 @default.
• W4285272257 cites W2059226882 @default.
• W4285272257 cites W2063059290 @default.
• W4285272257 cites W2067101667 @default.
• W4285272257 cites W2068577862 @default.
• W4285272257 cites W2069344019 @default.
• W4285272257 cites W2069746135 @default.
• W4285272257 cites W2073527872 @default.
• W4285272257 cites W2073804852 @default.
• W4285272257 cites W2074484094 @default.
• W4285272257 cites W2074969877 @default.
• W4285272257 cites W2077133240 @default.
• W4285272257 cites W2077368656 @default.
• W4285272257 cites W2082239463 @default.
• W4285272257 cites W2089115060 @default.
• W4285272257 cites W2094412188 @default.
• W4285272257 cites W2095536698 @default.
• W4285272257 cites W2095922031 @default.
• W4285272257 cites W2102333114 @default.
• W4285272257 cites W2106343435 @default.
• W4285272257 cites W2107443615 @default.
• W4285272257 cites W2117527662 @default.
• W4285272257 cites W2126224336 @default.
• W4285272257 cites W2136211705 @default.
• W4285272257 cites W2144050347 @default.
• W4285272257 cites W2147743267 @default.
• W4285272257 cites W2149729351 @default.
• W4285272257 cites W2164301661 @default.
• W4285272257 cites W2210064924 @default.
• W4285272257 cites W2221854285 @default.
• W4285272257 cites W2282578395 @default.
• W4285272257 cites W2313380081 @default.
• W4285272257 cites W2317156118 @default.
• W4285272257 cites W2319354469 @default.
• W4285272257 cites W2319645577 @default.
• W4285272257 cites W2319988805 @default.
• W4285272257 cites W2326050746 @default.
• W4285272257 cites W2329247413 @default.
• W4285272257 cites W2330441518 @default.
• W4285272257 cites W2411101553 @default.
• W4285272257 cites W2461328805 @default.
• W4285272257 cites W2474220615 @default.
• W4285272257 cites W2479632217 @default.
• W4285272257 cites W2500945718 @default.
• W4285272257 cites W2506242350 @default.
• W4285272257 cites W2518566019 @default.
• W4285272257 cites W2524524179 @default.
• W4285272257 cites W2528535900 @default.
• W4285272257 cites W2549149855 @default.
• W4285272257 cites W2590914539 @default.
• W4285272257 cites W2594167468 @default.
• W4285272257 cites W2615032787 @default.
• W4285272257 cites W2620648773 @default.
• W4285272257 cites W2767278562 @default.
• W4285272257 cites W2789833420 @default.
• W4285272257 cites W2792220591 @default.

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