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- W4285332619 abstract "Contamination is the most common and arguably the most significant problem scientists are facing in experimental surface science research that is practiced in the presence of gases. It is fair to say that contamination problems are often worse with ambient pressures compared to conventional experiments in vacuum. It is one of the main reasons for poor reproducibility in this field and in relevant basic and applied research fields like heterogeneous catalysis and electrochemistry. Whilst some type of contaminants are more innocent and only hinder quantitative analysis, some are harmful as they change the outcome of the experiments. In this chapter, the potential sources of contamination are summarized and some solutions are suggested. Examples of commonly observed contaminants such as hydrocarbons, oxygenated hydrocarbons, and adsorbed species of traces gases are presented. The scope of this chapter is restricted to ambient pressure x-ray photoelectron spectroscopy and infrared reflection absorption spectroscopy studies on single crystal surfaces, but similar problems exist on other sample surfaces or with other techniques such as x-ray absorption spectroscopy and sum frequency generation spectroscopy." @default.
- W4285332619 created "2022-07-14" @default.
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- W4285332619 date "2021-11-11" @default.
- W4285332619 modified "2023-10-13" @default.
- W4285332619 title "Contamination Issues in Ambient Pressure Experiments" @default.
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- W4285332619 doi "https://doi.org/10.1021/bk-2021-1396.ch011" @default.
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