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• W4285341665 endingPage "332" @default.
• W4285341665 startingPage "307" @default.
• W4285341665 abstract "One of the long-standing paradoxes in chemistry is that the molecular species of greatest interest are often highly reactive chemical intermediates and thus present only at vanishingly small concentrations under typical steady state conditions. This has proven both a key frustration and powerful motivation for physical chemists in probing such species, particularly for high resolution laser spectroscopic methods in the infrared. Over the past 4-5 decades, this fundamental sensitivity challenge has stimulated the development of many novel techniques for efficient generation, cooling, and infrared probing of such transient chemical intermediates, achieving increasingly sophisticated levels of spectroscopic detail, chemical insight, and a testbed for comparison with first principles ab initio quantum calculations. Two of the pioneering contributors to this scientific arena have been George Pimentel and C. Bradley Moore, both responsible for nourishing David J. Nesbitt’s (DJN’s) own enduring fascination with spectroscopic IR study of elusive chemical intermediates. This chapter is not intended to provide a comprehensive review of this large and enormously successful field, but it rather more simply attempts to capture a few selective “Moore-centric” snapshots of the Nesbitt group scientific evolution, specifically in i) advances by Pimentel for the original development of rapid scan flash kinetic spectroscopy based on spectrometers with rapidly rotating IR gratings, ii) the modernization/extension of these methods in the Moore group toward the first high resolution IR laser spectroscopy of singlet/triplet methylene 1,3CH2 diradical, and finally to iii) the development of slit supersonic discharge expansion methods at JILA for sub-Doppler infrared laser study of multiple radicals, jet cooled molecular ions, and highly reactive chemical intermediates." @default.
• W4285341665 created "2022-07-14" @default.
• W4285341665 creator A5049124852 @default.
• W4285341665 creator A5070640058 @default.
• W4285341665 creator A5084872177 @default.
• W4285341665 date "2021-10-27" @default.
• W4285341665 modified "2023-09-27" @default.
• W4285341665 title "High Resolution Infrared Spectroscopy of Highly Reactive Chemical Intermediates: Berkeley Inspiration and a C.B. Moore Retrospective" @default.
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