FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4285384034> ?p ?o ?g. }

• W4285384034 endingPage "101033" @default.
• W4285384034 startingPage "101033" @default.
• W4285384034 abstract "Deep eutectic electrolytes are a recent focus in the development of energy-related fields, particularly in the area of Li batteries to combine with safer, sustainable, and cost-effective electrolytes. We herein describe a solvent-free synthetic route to ion-conductive polymers from metal salt/amide-based deep eutectic monomers (DEMs), which were prepared by mixing amido-containing solid monomers with metal salts under suitable feed ratios. N-Isopropyl acrylamide (NIPAM) and N-vinylacetamide (NVA) were selected as vinyl monomers bearing an amido functional group that can act as a hydrogen bond donor. Lithium chloride (LiCl), zinc chloride (ZnCl2), and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), which can act as hydrogen bond acceptors, were employed as metal salts. The simple mixing of NIPAM with solid LiTFSI in a 5:1 M ratio at 60 °C for 0.5 h afforded liquid NIPAM/0.2LiTFSI, which exhibited the characteristic eutectic effect. By mixing NIPMA with ZnCl2 in a suitable feed ratio, NIPAM/0.25ZnCl2 was obtained as a white turbid liquid at room temperature. Similarly, NVA/0.2LiCl and NVA/0.2LiTFSI were obtained as transparent liquids from solid NVA. In addition, the thermally-induced free-radical polymerization of the metal salt/amide-based DEMs in the bulk and in solution resulted in the formation of the corresponding polymers. Poly(NVA/0.2LiTFSI) exhibited the highest ionic conductivity of 2.83 × 10−6 S/cm at 50 °C. Polymeric products were also obtained by photoinduced radical polymerization from liquid DEMs without the use of volatile organic solvents under an air environment. These results reveal that the DEMs developed in this study can provide a green and sustainable process for the radically-induced production of novel ion-conductive polymers in air." @default.
• W4285384034 created "2022-07-14" @default.
• W4285384034 creator A5012284245 @default.
• W4285384034 creator A5013710721 @default.
• W4285384034 creator A5049881848 @default.
• W4285384034 creator A5071758694 @default.
• W4285384034 date "2022-12-01" @default.
• W4285384034 modified "2023-10-01" @default.
• W4285384034 title "Design of metal salt/amide-based deep eutectic monomers toward sustainable production of ion-conductive polymers by radical polymerization" @default.
• W4285384034 cites W1967410318 @default.
• W4285384034 cites W1994008728 @default.
• W4285384034 cites W2003734409 @default.
• W4285384034 cites W2005877813 @default.
• W4285384034 cites W2027186687 @default.
• W4285384034 cites W2031408985 @default.
• W4285384034 cites W2032958802 @default.
• W4285384034 cites W2048869030 @default.
• W4285384034 cites W2052977210 @default.
• W4285384034 cites W2053308177 @default.
• W4285384034 cites W2055308765 @default.
• W4285384034 cites W2065820312 @default.
• W4285384034 cites W2065900724 @default.
• W4285384034 cites W2066838491 @default.
• W4285384034 cites W2082388542 @default.
• W4285384034 cites W2092573773 @default.
• W4285384034 cites W2124985647 @default.
• W4285384034 cites W2125680831 @default.
• W4285384034 cites W2144817668 @default.
• W4285384034 cites W2150844935 @default.
• W4285384034 cites W2230578498 @default.
• W4285384034 cites W2233256111 @default.
• W4285384034 cites W2234110102 @default.
• W4285384034 cites W2280088384 @default.
• W4285384034 cites W2300312929 @default.
• W4285384034 cites W2319128214 @default.
• W4285384034 cites W2320378213 @default.
• W4285384034 cites W2321005010 @default.
• W4285384034 cites W2523204319 @default.
• W4285384034 cites W2527744548 @default.
• W4285384034 cites W2531080026 @default.
• W4285384034 cites W2604669202 @default.
• W4285384034 cites W2739170784 @default.
• W4285384034 cites W2761445323 @default.
• W4285384034 cites W2763688997 @default.
• W4285384034 cites W2774331951 @default.
• W4285384034 cites W2803637172 @default.
• W4285384034 cites W2921482998 @default.
• W4285384034 cites W3000067905 @default.
• W4285384034 cites W3008329501 @default.
• W4285384034 cites W3009028754 @default.
• W4285384034 cites W3014332055 @default.
• W4285384034 cites W3015751415 @default.
• W4285384034 cites W3017304590 @default.
• W4285384034 cites W3044295661 @default.
• W4285384034 cites W3044473144 @default.
• W4285384034 cites W3120003760 @default.
• W4285384034 cites W3133617191 @default.
• W4285384034 cites W3149392349 @default.
• W4285384034 cites W3206018157 @default.
• W4285384034 cites W3209454047 @default.
• W4285384034 doi "https://doi.org/10.1016/j.mtchem.2022.101033" @default.
• W4285384034 hasPublicationYear "2022" @default.
• W4285384034 type Work @default.
• W4285384034 citedByCount "1" @default.
• W4285384034 countsByYear W42853840342023 @default.
• W4285384034 crossrefType "journal-article" @default.
• W4285384034 hasAuthorship W4285384034A5012284245 @default.
• W4285384034 hasAuthorship W4285384034A5013710721 @default.
• W4285384034 hasAuthorship W4285384034A5049881848 @default.
• W4285384034 hasAuthorship W4285384034A5071758694 @default.
• W4285384034 hasConcept C111998727 @default.
• W4285384034 hasConcept C154881586 @default.
• W4285384034 hasConcept C161790260 @default.
• W4285384034 hasConcept C166940927 @default.
• W4285384034 hasConcept C178790620 @default.
• W4285384034 hasConcept C179104552 @default.
• W4285384034 hasConcept C18168003 @default.
• W4285384034 hasConcept C185592680 @default.
• W4285384034 hasConcept C188027245 @default.
• W4285384034 hasConcept C192562407 @default.
• W4285384034 hasConcept C2778439535 @default.
• W4285384034 hasConcept C2780026712 @default.
• W4285384034 hasConcept C2780371645 @default.
• W4285384034 hasConcept C44228677 @default.
• W4285384034 hasConcept C521977710 @default.
• W4285384034 hasConceptScore W4285384034C111998727 @default.
• W4285384034 hasConceptScore W4285384034C154881586 @default.
• W4285384034 hasConceptScore W4285384034C161790260 @default.
• W4285384034 hasConceptScore W4285384034C166940927 @default.
• W4285384034 hasConceptScore W4285384034C178790620 @default.
• W4285384034 hasConceptScore W4285384034C179104552 @default.
• W4285384034 hasConceptScore W4285384034C18168003 @default.
• W4285384034 hasConceptScore W4285384034C185592680 @default.
• W4285384034 hasConceptScore W4285384034C188027245 @default.
• W4285384034 hasConceptScore W4285384034C192562407 @default.
• W4285384034 hasConceptScore W4285384034C2778439535 @default.
• W4285384034 hasConceptScore W4285384034C2780026712 @default.
• W4285384034 hasConceptScore W4285384034C2780371645 @default.

• next