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- W4285386468 abstract "Herein, we present an efficient and straightforward strategy enabling access to 2,3-disubstituted benzo[b]furans. The whole synthetic process proceeds via a domino intermolecular Sonogashira coupling of 2-(2-bromophenoxy)-1-phenylethan-1-ones/alkyl 2-(2-bromophenoxy)acetates/2-(2-bromophenoxy)acetonitrile/1-(2-bromophenoxy)propan-2-one with terminal acetylenes followed by an intramolecular carbanion-yne cyclization in a 5-exo-dig manner and subsequent double-bond isomerization. Notably, two C-C bonds have been constructed in a one-pot manner and a wide variety of (3-benzylbenzofuran-2-yl)(phenyl)methanones were accomplished with good functional group tolerance." @default.
- W4285386468 created "2022-07-14" @default.
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- W4285386468 date "2022-07-14" @default.
- W4285386468 modified "2023-09-24" @default.
- W4285386468 title "Intermolecular Sonogashira Coupling and Intramolecular 5-<i>Exo</i>-<i>dig</i> Cycloisomerization Cascade: A One-Pot Pathway for Accessing (3-Benzylbenzofuran-2-yl)(phenyl)methanones" @default.
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- W4285386468 doi "https://doi.org/10.1021/acs.joc.2c01101" @default.
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