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- W4285386827 abstract "The design and development of an Ag(I)-promoted, highly diastereoselective cycloisomerization strategy for the synthesis of syn-1,2-diarylpyrrolo[1,2-a]indol-3-ones from N-alkynyl-indole-2-carbinols is reported. The H218O control experiment and identification of 18O-labeled product suggested the involvement of an external water. The 7-azaindole substrates showned a distinct reactivity to give the (Z)-8-benzylideneoxazolo[3',4':1,5]pyrrolo[2,3-b]pyridines. Key features of this strategy are its 100% atom economy, access to important heterocycles, diverse substrate scope, yields up to 95%, operationally simple procedure, and distinct reactivity of indole vs 7-azaindoles." @default.
- W4285386827 created "2022-07-14" @default.
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- W4285386827 date "2022-07-14" @default.
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- W4285386827 title "Ag(I)-Promoted, Diastereoselective Cyclo-isomerization of <i>N</i>-Alkynyl-7-azaindole-2-carbinols. Selective Synthesis of <i>syn</i>-1,2-Diarylpyrrolo[1,2-<i>a</i>]indol-3-ones and (<i>Z</i>)-8-Benzylideneoxazolo[3′,4′’:1,5]pyrrolo[2,3-<i>b</i>]pyridines" @default.
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- W4285386827 doi "https://doi.org/10.1021/acs.orglett.2c02179" @default.
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