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- W4285391490 abstract "Abstract Novel ZrSn 1− x Co x O 4− δ catalysts for the direct decomposition of nitrous oxide (N 2 O) were synthesized using a co‐precipitation method. Metastable ZrSnO 4 with an α‐PbO 2 ‐type structure was used as the mother solid because of its interstitial open spaces derived from its lattice distortion that may be effective for N 2 O adsorption. The doping of Co 2+/3+ into the ZrSnO 4 lattice improved the N 2 O decomposition activity, likely owing to the enhancement of the redox properties and the increase in the number of oxygen vacancies. Among the prepared catalysts, Zr 1.17 Sn 0.73 Co 0.10 O 4− δ exhibited the highest activity decomposing N 2 O completely decomposed at 550°C. In addition, the Zr 1.17 Sn 0.73 Co 0.10 O 4− δ catalyst showed high durability in the presence of CO 2 , O 2 , and H 2 O vapor." @default.
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- W4285391490 date "2022-07-27" @default.
- W4285391490 modified "2023-10-12" @default.
- W4285391490 title "Novel cobalt‐doped ZrSnO<sub>4</sub> catalysts for direct nitrous oxide decomposition" @default.
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- W4285391490 doi "https://doi.org/10.1111/ijac.14121" @default.
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