FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4285403253> ?p ?o ?g. }

• W4285403253 endingPage "463346" @default.
• W4285403253 startingPage "463346" @default.
• W4285403253 abstract "• The transient dispersion in multi-capillary systems with diffusional bridging is studied. • Mathematical expressions are established for a generic N-capillary system. • Insights extending beyond those obtained from a dual capillary model are obtained. • When n tends to infinity, plate heights increase with log e of channel length in 3D. • When time tends to infinity, plate heights increase with log e of (N-1) in 3D. We report on a generic mathematical study of the transient plate height regime in bundles of polydisperse capillaries with diffusional bridging. I.e., we have investigated how the plate height in such systems can be expected to vary with the residence time, or equivalently, with the column length, before reaching a long-time limit wherein the plate height becomes constant. This is important because, in case of systems with a large number of capillaries ( N ), the transient regime solution is practically much more relevant than the long-time limit solution. The problem has been investigated using a simplified, yet representative geometry that is amenable to a semi-analytical solution, only requiring a numerical integration of the velocity field across a line (2D geometries) or a square or rectangle (3D geometries). The availability of this semi-analytical approach allows to consider the required large number of different random capillary diameter drawings (order of 10,000) needed to establish a sufficiently averaged result (deviation from true mean on the order of 1%). The general solution could be simplified into a set of two-parameter expressions describing either the long-time limit (τ→∞) as well as that of an infinite number of capillaries (N→∞). The combinations of N and τ where these expressions are valid to within an accuracy of 5% could be delimited with simple analytical expressions as well. It has also been observed that the long-time limit solution for the additional plate height (Δh τ→∞ ) remains dependant on the number of capillaries N, even when N tends to infinity. It is found that Δh τ→∞ can be expected to increase in proportion with N-1 (2D-case) or with ln(N-1) (3D-case). This dependency of Δh τ→∞ on N is a result that is not obtained when modelling the capillary bundle using a representative binary capillary system approach as has been done up-till-now in literature." @default.
• W4285403253 created "2022-07-14" @default.
• W4285403253 creator A5016972901 @default.
• W4285403253 creator A5075064110 @default.
• W4285403253 creator A5086862924 @default.
• W4285403253 date "2022-08-01" @default.
• W4285403253 modified "2023-10-14" @default.
• W4285403253 title "Transient Taylor-Aris dispersion in N-capillary systems: Convergence properties of the band broadening in polydisperse multi-capillary columns with diffusional bridging" @default.
• W4285403253 cites W2051487106 @default.
• W4285403253 cites W2075788497 @default.
• W4285403253 cites W2084084520 @default.
• W4285403253 cites W2102123503 @default.
• W4285403253 cites W2293666145 @default.
• W4285403253 cites W2793940587 @default.
• W4285403253 cites W3021960049 @default.
• W4285403253 cites W3035330085 @default.
• W4285403253 cites W3134829646 @default.
• W4285403253 cites W3193991796 @default.
• W4285403253 cites W3209489323 @default.
• W4285403253 doi "https://doi.org/10.1016/j.chroma.2022.463346" @default.
• W4285403253 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35882075" @default.
• W4285403253 hasPublicationYear "2022" @default.
• W4285403253 type Work @default.
• W4285403253 citedByCount "3" @default.
• W4285403253 countsByYear W42854032532023 @default.
• W4285403253 crossrefType "journal-article" @default.
• W4285403253 hasAuthorship W4285403253A5016972901 @default.
• W4285403253 hasAuthorship W4285403253A5075064110 @default.
• W4285403253 hasAuthorship W4285403253A5086862924 @default.
• W4285403253 hasConcept C121332964 @default.
• W4285403253 hasConcept C134306372 @default.
• W4285403253 hasConcept C185592680 @default.
• W4285403253 hasConcept C196806460 @default.
• W4285403253 hasConcept C204402833 @default.
• W4285403253 hasConcept C2524010 @default.
• W4285403253 hasConcept C33923547 @default.
• W4285403253 hasConcept C57879066 @default.
• W4285403253 hasConcept C97355855 @default.
• W4285403253 hasConceptScore W4285403253C121332964 @default.
• W4285403253 hasConceptScore W4285403253C134306372 @default.
• W4285403253 hasConceptScore W4285403253C185592680 @default.
• W4285403253 hasConceptScore W4285403253C196806460 @default.
• W4285403253 hasConceptScore W4285403253C204402833 @default.
• W4285403253 hasConceptScore W4285403253C2524010 @default.
• W4285403253 hasConceptScore W4285403253C33923547 @default.
• W4285403253 hasConceptScore W4285403253C57879066 @default.
• W4285403253 hasConceptScore W4285403253C97355855 @default.
• W4285403253 hasLocation W42854032531 @default.
• W4285403253 hasLocation W42854032532 @default.
• W4285403253 hasOpenAccess W4285403253 @default.
• W4285403253 hasPrimaryLocation W42854032531 @default.
• W4285403253 hasRelatedWork W1997243919 @default.
• W4285403253 hasRelatedWork W2055590620 @default.
• W4285403253 hasRelatedWork W2144139276 @default.
• W4285403253 hasRelatedWork W2317766194 @default.
• W4285403253 hasRelatedWork W2565706996 @default.
• W4285403253 hasRelatedWork W2601023693 @default.
• W4285403253 hasRelatedWork W2626211168 @default.
• W4285403253 hasRelatedWork W3029169769 @default.
• W4285403253 hasRelatedWork W4225386803 @default.
• W4285403253 hasRelatedWork W2127428110 @default.
• W4285403253 hasVolume "1678" @default.
• W4285403253 isParatext "false" @default.
• W4285403253 isRetracted "false" @default.
• W4285403253 workType "article" @default.