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- W4285405428 endingPage "119867" @default.
- W4285405428 startingPage "119867" @default.
- W4285405428 abstract "A novel method is reported for the preparation of a hybrid gibbsite-cellulose nanofibril (CNF) nanocomposite film with improved wet and dry mechanical properties and barrier properties. A gibbsite and cationic CNF dispersion was dewatered at pH 7 to prepare well-ordered films. Thereafter, the charge on gibbsite was reversed by dipping the film in pH 12 water to induce an ionic interaction between CNFs and gibbsite, enhancing the film properties; modulus improved from 9 GPa to 12 GPa, with a maintained strain-at-break of 6 % and tensile strength of 190 MPa. Additionally, the charge-reversed film swelled a factor of 24 less than a film without any gibbsite. At 23 °C and 80 % RH, the oxygen barrier properties were improved by a factor of 28, to a value of 18 ml·μm·m−2·kPa−1·24 h−1 and the water vapour barrier properties were improved by a factor of 12, to a value of 105 g·μm·m−2·kPa−1·24 h−1." @default.
- W4285405428 created "2022-07-14" @default.
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- W4285405428 date "2022-11-01" @default.
- W4285405428 modified "2023-10-15" @default.
- W4285405428 title "Water-resistant hybrid cellulose nanofibril films prepared by charge reversal on gibbsite nanoclays" @default.
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- W4285405428 doi "https://doi.org/10.1016/j.carbpol.2022.119867" @default.
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