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- W4285489715 abstract "Hazardous waste alkaline batteries and waste fatty acids significantly threaten the environment. In this study, waste alkaline batteries were simply transferred to r-MnZn catalysts, which were then applied in the ketonization of fatty acids. The assessment results show that r-MnZn can efficiently convert n-octanoic acid to 8-pentadecanone. The conversion and yield are evaluated as 100% and 92.9%, respectively, which are much better than those of TiO2, ZrO2, CeO2 and other metal oxides. The excellent catalytic efficiency is derived from the MnO2 nanorods in r-MnZn materials which are characterized by XRD, TEM, and XPS. In addition, when using different kinds of fatty acids in ketonization, longer carbon chains require a higher activation energy, and the conversion of fatty acids was lower. Furthermore, the ketone products have a short carbon chain that induces side reactions, leading to a low yield. The above results indicate that r-MnZn is an efficient catalyst applied in the ketonization of fatty acids." @default.
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- W4285489715 date "2022-10-01" @default.
- W4285489715 modified "2023-09-30" @default.
- W4285489715 title "Waste alkaline Mn–Zn batteries as efficient catalysts applied in ketonization of fatty acids" @default.
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- W4285489715 doi "https://doi.org/10.1016/j.scp.2022.100787" @default.
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