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- W4285494684 abstract "A new Co-catalyzed sequential C-C and C-F activation of gem-difluorinated cyclopropanes (gem-FCPs) to form nucleophilic fluoroallylcobalt, followed by addition to aldehydes, is reported. The protocol features the regioselective cleavage of dual chemical bonds of readily available gem-FCPs to prepare easily separable linear (Z)- and (E)-fluorinated homoallylic alcohols with a broad scope. This discovery established a new strategy for the efficient transformation of gem-FCPs as well as the synthesis of challenging fluorinated homoallylic alcohols." @default.
- W4285494684 created "2022-07-15" @default.
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- W4285494684 date "2022-07-14" @default.
- W4285494684 modified "2023-10-16" @default.
- W4285494684 title "Cobalt-Catalyzed Fluoroallyllation of Carbonyls via C–C Activation of <i>gem</i>-Difluorocyclopropanes" @default.
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- W4285494684 doi "https://doi.org/10.1021/acs.orglett.2c01821" @default.
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