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• W4285593914 abstract "Abstract Glasses of the formula 40Li 2 O· x Sb 2 O 3 ·(60– x )B 2 O 3 (0 ≤ x ≤ 40 mol%) were prepared using the melt quenching technique. XRD, FTIR spectroscopy, SEM, density and dc conductivity were studied. A phase separation was observed in as-prepared glass samples that contain a concentration of Sb 2 O 3 ≥ 25 mol%. Moreover, crystalline phases of Li 5 Sb 3 O 8 , Li 3 SbO 4 and LiSbO 3 were found in the 40Li 2 O·40Sb 2 O 3 ·20B 2 O 3 glass sample after thermal treatment at 600 °C for 4 h. N 4 decreased slightly with increasing Sb 2 O 3 content. The contribution to N 4 from Li 2 O and Sb 2 O 3 was separated. The negative contribution of Sb 2 O 3 to N 4 was due to the association of Sb 2 O 3 and Li 2 O to form Li 5 Sb 3 O 8 , Li 3 SbO 4 and LiSbO 3 phases and acting as a former. The formed Li 5 Sb 3 O 8 , Li 3 SbO 4 phases having low migration energy and rich with Li + ions exhibited a high mobility. Density and molar volume increased with increasing Sb 2 O 3 content. The abrupt increase in the conductivity by about 4 orders in magnitude for Sb 2 O 3 ≥ 25 mol% is correlated with the presence of clusters rich by Li + and Sb +3 ions that have low migration energies and the increase in the free volume." @default.
• W4285593914 created "2022-07-16" @default.
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• W4285593914 date "2022-07-29" @default.
• W4285593914 modified "2023-10-13" @default.
• W4285593914 title "Structure and related physical properties of Li₂O-Sb₂O₃-B₂O₃ glasses" @default.
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• W4285593914 doi "https://doi.org/10.1088/1402-4896/ac8184" @default.
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