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- W4285676636 abstract "Herein, we report an unprecedented intramolecular cross-nucleophile coupling strategy of indole tethered β-amino acrylates using a catalyst system combining λ3-iodanes and Lewis acids to achieve the chemodivergent synthesis of three unique alkaloid skeletons. It was worth noting that the acquisition of spiroindolenines and azepino[4,5-b]indoles derivatives was switchable with choice of the Lewis acids. Moreover, the polycyclic spiroindolines containing a lactone fragment could also be accessed for the first time via cross-nucleophile coupling cascade intramolecular condensation sequence." @default.
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- W4285676636 date "2022-07-17" @default.
- W4285676636 modified "2023-10-18" @default.
- W4285676636 title "λ<sup>3</sup>-Iodane/Lewis Acid Mediated Intramolecular Cross-Nucleophile Coupling of β-Amino Acrylates: Chemodivergent Syntheses of Indole Alkaloidal Frameworks" @default.
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- W4285676636 doi "https://doi.org/10.1021/acs.orglett.2c02060" @default.
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