FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4285681443> ?p ?o ?g. }

• W4285681443 endingPage "138109" @default.
• W4285681443 startingPage "138109" @default.
• W4285681443 abstract "In this work, we conceived a novel vis/H2O2/Fe3+/nitrilotriacetic acid (NTA)/g-C3N4 system to address the bottlenecks of traditional homogeneous photo-Fenton reactions, i.e., the narrow pH application range and unsustainable electron supply by the ligand to metal charge transfer (LMCT) process. A strong synergistic effect was observed with efficient organic contaminant degradation in a broad pH range (3–8), and hydroxyl radical (HO•) was proved to be the primary active species. Intriguingly, we found that the mechanism of rate-limiting Fe3+ reduction process was highly pH-dependent. At acidic condition (pH 3.0), the reduction of Fe3+ was dominated by direct photogenerated electron (e−) transfer and LMCT reaction. However, as the pH increased to 7.0, it gradually converted into a superoxide radical (O2•−) mediated reduction process, which was mainly attributed to the enhanced electrostatic repulsion between g-C3N4 and iron species, and the species transformation from protonated HO2• to more active deprotonated O2•−. Notably, H2O2 played a triple role in this system including (1) serving as the precursor of O2•− (2) scavenging photogenerated holes (h+) to complete the closed-loop of photocatalytic reaction and (3) boosting the generation of HO•. Finally, the vis/H2O2/Fe3+/NTA/g-C3N4 system also featured with a strong water matrix resistance capacity (e.g., chloride, bicarbonate, Ca2+/Mg2+ and humic acid), which enables it a promising platform for practical wastewater purification." @default.
• W4285681443 created "2022-07-17" @default.
• W4285681443 creator A5010128689 @default.
• W4285681443 creator A5019255400 @default.
• W4285681443 creator A5023363049 @default.
• W4285681443 creator A5034041737 @default.
• W4285681443 creator A5044078662 @default.
• W4285681443 creator A5077096394 @default.
• W4285681443 creator A5079842107 @default.
• W4285681443 creator A5082744133 @default.
• W4285681443 creator A5091495007 @default.
• W4285681443 date "2022-12-01" @default.
• W4285681443 modified "2023-10-18" @default.
• W4285681443 title "Extending semiconductor-based photo-fenton reaction to circumneutral pH using chelating agents: The overlooked role of pH on the reduction mechanism of Fe3+" @default.
• W4285681443 cites W1967058399 @default.
• W4285681443 cites W1967984071 @default.
• W4285681443 cites W1968810061 @default.
• W4285681443 cites W1980857424 @default.
• W4285681443 cites W1983228601 @default.
• W4285681443 cites W1988907910 @default.
• W4285681443 cites W2003714836 @default.
• W4285681443 cites W2010942241 @default.
• W4285681443 cites W2036301901 @default.
• W4285681443 cites W2051475927 @default.
• W4285681443 cites W2058187935 @default.
• W4285681443 cites W2061778764 @default.
• W4285681443 cites W2067155849 @default.
• W4285681443 cites W2070007460 @default.
• W4285681443 cites W2074378541 @default.
• W4285681443 cites W2087879344 @default.
• W4285681443 cites W2097943500 @default.
• W4285681443 cites W2122726699 @default.
• W4285681443 cites W2325465628 @default.
• W4285681443 cites W2489426426 @default.
• W4285681443 cites W2573048270 @default.
• W4285681443 cites W2593124874 @default.
• W4285681443 cites W2606644027 @default.
• W4285681443 cites W2609959997 @default.
• W4285681443 cites W2735379011 @default.
• W4285681443 cites W2765633645 @default.
• W4285681443 cites W2792892989 @default.
• W4285681443 cites W2793961045 @default.
• W4285681443 cites W2803010936 @default.
• W4285681443 cites W2889768248 @default.
• W4285681443 cites W2891506290 @default.
• W4285681443 cites W2893209717 @default.
• W4285681443 cites W2911754270 @default.
• W4285681443 cites W2982197111 @default.
• W4285681443 cites W2990523160 @default.
• W4285681443 cites W2994238016 @default.
• W4285681443 cites W2995756396 @default.
• W4285681443 cites W3000003782 @default.
• W4285681443 cites W3011681035 @default.
• W4285681443 cites W3028255464 @default.
• W4285681443 cites W3031859674 @default.
• W4285681443 cites W3040695216 @default.
• W4285681443 cites W3045232192 @default.
• W4285681443 cites W3047720485 @default.
• W4285681443 cites W3082142772 @default.
• W4285681443 cites W3087442696 @default.
• W4285681443 cites W3088073223 @default.
• W4285681443 cites W3093303391 @default.
• W4285681443 cites W3094172908 @default.
• W4285681443 cites W3097285974 @default.
• W4285681443 cites W3100937784 @default.
• W4285681443 cites W3106938180 @default.
• W4285681443 cites W3119755811 @default.
• W4285681443 cites W3122323284 @default.
• W4285681443 cites W3143185313 @default.
• W4285681443 cites W3156710449 @default.
• W4285681443 cites W3164379454 @default.
• W4285681443 cites W3165242037 @default.
• W4285681443 cites W3171118711 @default.
• W4285681443 cites W3183054553 @default.
• W4285681443 cites W3183407769 @default.
• W4285681443 cites W3194885863 @default.
• W4285681443 cites W3198508097 @default.
• W4285681443 cites W3210726884 @default.
• W4285681443 cites W3211760050 @default.
• W4285681443 cites W3213129025 @default.
• W4285681443 cites W3214604879 @default.
• W4285681443 cites W4200568727 @default.
• W4285681443 doi "https://doi.org/10.1016/j.cej.2022.138109" @default.
• W4285681443 hasPublicationYear "2022" @default.
• W4285681443 type Work @default.
• W4285681443 citedByCount "4" @default.
• W4285681443 countsByYear W42856814432023 @default.
• W4285681443 crossrefType "journal-article" @default.
• W4285681443 hasAuthorship W4285681443A5010128689 @default.
• W4285681443 hasAuthorship W4285681443A5019255400 @default.
• W4285681443 hasAuthorship W4285681443A5023363049 @default.
• W4285681443 hasAuthorship W4285681443A5034041737 @default.
• W4285681443 hasAuthorship W4285681443A5044078662 @default.
• W4285681443 hasAuthorship W4285681443A5077096394 @default.
• W4285681443 hasAuthorship W4285681443A5079842107 @default.
• W4285681443 hasAuthorship W4285681443A5082744133 @default.
• W4285681443 hasAuthorship W4285681443A5091495007 @default.
• W4285681443 hasConcept C118629725 @default.

• next