Matches in SemOpenAlex for { <https://semopenalex.org/work/W4285802587> ?p ?o ?g. }
- W4285802587 abstract "Abstract The selective photo‐oxidation of biomass‐derived 5‐hydroxymethylfurfural (HMF) to 2,5‐furandicarboxylic acid (FDCA) is important due to its substitute‐role in polyester‐fabrication. Here, a titanium‐cluster based metal‐covalent organic framework nanosheet has been synthesized through the covalent‐coupling between Ti 6 ‐NH 2 and benzotrithiophene tricarbaldehyde (BTT). The integration of them endows the nanosheet with a visible‐light‐adsorption region, effective electron‐hole separation‐efficiency and suitable photo‐oxidation ability. Specifically, its photo‐selectivity for HMF‐to‐FDCA can be >95 % with ≈100 % conversion, which is more than 2, 5, and 10 times higher than MOF‐901 (43 %), Ti 6 ‐NH 2 (19 %) and under‐darkness (9 %), respectively. Notably, an O 2 ‐based mechanism is proposed and the vital roles of Ti 6 ‐NH 2 and BTT are verified by DFT calculations. This work might facilitate the exploration of porous‐crystalline‐catalysts for selective biomass‐valorization." @default.
- W4285802587 created "2022-07-19" @default.
- W4285802587 creator A5003081708 @default.
- W4285802587 creator A5020746135 @default.
- W4285802587 creator A5023725539 @default.
- W4285802587 creator A5028045589 @default.
- W4285802587 creator A5036897639 @default.
- W4285802587 creator A5041144994 @default.
- W4285802587 creator A5054485071 @default.
- W4285802587 creator A5070358168 @default.
- W4285802587 creator A5071535731 @default.
- W4285802587 creator A5077731514 @default.
- W4285802587 creator A5078813898 @default.
- W4285802587 date "2022-08-03" @default.
- W4285802587 modified "2023-10-14" @default.
- W4285802587 title "Covalent‐Bonding Oxidation Group and Titanium Cluster to Synthesize a Porous Crystalline Catalyst for Selective Photo‐Oxidation Biomass Valorization" @default.
- W4285802587 cites W1677747913 @default.
- W4285802587 cites W1916659016 @default.
- W4285802587 cites W1969929163 @default.
- W4285802587 cites W1977523466 @default.
- W4285802587 cites W2003181278 @default.
- W4285802587 cites W2007661885 @default.
- W4285802587 cites W2089686026 @default.
- W4285802587 cites W2105503244 @default.
- W4285802587 cites W2110003117 @default.
- W4285802587 cites W2119970259 @default.
- W4285802587 cites W2163156526 @default.
- W4285802587 cites W2180529092 @default.
- W4285802587 cites W2295691216 @default.
- W4285802587 cites W2297279974 @default.
- W4285802587 cites W2307962705 @default.
- W4285802587 cites W2342348238 @default.
- W4285802587 cites W2564427513 @default.
- W4285802587 cites W2577276844 @default.
- W4285802587 cites W2592308660 @default.
- W4285802587 cites W2758937586 @default.
- W4285802587 cites W2763056250 @default.
- W4285802587 cites W2891259798 @default.
- W4285802587 cites W2896044205 @default.
- W4285802587 cites W2944431249 @default.
- W4285802587 cites W2947943028 @default.
- W4285802587 cites W2967316421 @default.
- W4285802587 cites W2977561728 @default.
- W4285802587 cites W2984973284 @default.
- W4285802587 cites W3023954158 @default.
- W4285802587 cites W3029815071 @default.
- W4285802587 cites W3030286671 @default.
- W4285802587 cites W3037101809 @default.
- W4285802587 cites W3044718315 @default.
- W4285802587 cites W3110276664 @default.
- W4285802587 cites W3111276287 @default.
- W4285802587 cites W3119925172 @default.
- W4285802587 cites W3137598272 @default.
- W4285802587 cites W3187143028 @default.
- W4285802587 cites W3187888768 @default.
- W4285802587 cites W3195392008 @default.
- W4285802587 cites W3196444941 @default.
- W4285802587 cites W3198446866 @default.
- W4285802587 cites W3201141622 @default.
- W4285802587 cites W3211802130 @default.
- W4285802587 cites W3216135324 @default.
- W4285802587 cites W4200334970 @default.
- W4285802587 cites W4206897972 @default.
- W4285802587 cites W4210286528 @default.
- W4285802587 cites W4210998571 @default.
- W4285802587 cites W4212808281 @default.
- W4285802587 cites W4213366727 @default.
- W4285802587 cites W4214683521 @default.
- W4285802587 cites W4221035152 @default.
- W4285802587 cites W4225380152 @default.
- W4285802587 cites W4226310188 @default.
- W4285802587 cites W4231740516 @default.
- W4285802587 cites W4232346994 @default.
- W4285802587 doi "https://doi.org/10.1002/ange.202209289" @default.
- W4285802587 hasPublicationYear "2022" @default.
- W4285802587 type Work @default.
- W4285802587 citedByCount "2" @default.
- W4285802587 countsByYear W42858025872023 @default.
- W4285802587 crossrefType "journal-article" @default.
- W4285802587 hasAuthorship W4285802587A5003081708 @default.
- W4285802587 hasAuthorship W4285802587A5020746135 @default.
- W4285802587 hasAuthorship W4285802587A5023725539 @default.
- W4285802587 hasAuthorship W4285802587A5028045589 @default.
- W4285802587 hasAuthorship W4285802587A5036897639 @default.
- W4285802587 hasAuthorship W4285802587A5041144994 @default.
- W4285802587 hasAuthorship W4285802587A5054485071 @default.
- W4285802587 hasAuthorship W4285802587A5070358168 @default.
- W4285802587 hasAuthorship W4285802587A5071535731 @default.
- W4285802587 hasAuthorship W4285802587A5077731514 @default.
- W4285802587 hasAuthorship W4285802587A5078813898 @default.
- W4285802587 hasConcept C111368507 @default.
- W4285802587 hasConcept C115540264 @default.
- W4285802587 hasConcept C118792377 @default.
- W4285802587 hasConcept C127313418 @default.
- W4285802587 hasConcept C127413603 @default.
- W4285802587 hasConcept C150394285 @default.
- W4285802587 hasConcept C161790260 @default.
- W4285802587 hasConcept C178790620 @default.
- W4285802587 hasConcept C179104552 @default.
- W4285802587 hasConcept C180577832 @default.