FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4285809991> ?p ?o ?g. }

• W4285809991 endingPage "121650" @default.
• W4285809991 startingPage "121650" @default.
• W4285809991 abstract "Recently, based on the mechanism of excited-state intramolecular proton transfer (ESIPT), a new fluorescent probe named 3-(benzo[d]thiazol-2-yl)-5-bromosalicylaldehyde-4N-phenyl thiosemicarbazone (BTT) was successfully synthesized [Analyst 146 (2021) 4348–4356.]. However, the importance of ESIPT processes of BTT probe and the mechanism of detecting Zn2+ ions have not been studied in detail. In this study, the photochemical behavior of ESIPT-chromophore and the photophysical changes of detecting Zn2+ ions were explained at the molecular level for the first time. The calculated spectral values were in agreement with the experiment. We not only confirmed the excited state hydrogen-bond strengthening by interaction region indicator (IRI), but also scanned the potential energy curves of BTT molecule in different electronic states, which confirmed that the hydrogen proton is easier to transfer in the first excited state. In addition, we had given the reasonable structure of the BTT-Zn2+ complex (L1) by comparing the binding free energies. The hole-electron distribution and interfragment charge transfer (IFCT) methods proved the excitation type of intraligand charge transfer (ILCT). Finally, the photophysical phenomenon of BTT for detecting Zn2+ ions is explained by calculating the electronic spectra and the energy gap (Egap) between the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO)." @default.
• W4285809991 created "2022-07-19" @default.
• W4285809991 creator A5020819410 @default.
• W4285809991 creator A5032103164 @default.
• W4285809991 creator A5054859377 @default.
• W4285809991 creator A5067608591 @default.
• W4285809991 creator A5077591572 @default.
• W4285809991 date "2022-12-01" @default.
• W4285809991 modified "2023-10-10" @default.
• W4285809991 title "Unveiling the sensing mechanism and luminescence property of a new ESIPT-based fluorescent sensor for detecting Zn2+" @default.
• W4285809991 cites W1968392598 @default.
• W4285809991 cites W1969066904 @default.
• W4285809991 cites W1982356449 @default.
• W4285809991 cites W1994940236 @default.
• W4285809991 cites W1995946575 @default.
• W4285809991 cites W2011215428 @default.
• W4285809991 cites W2012731941 @default.
• W4285809991 cites W2013294038 @default.
• W4285809991 cites W2026975368 @default.
• W4285809991 cites W2029033000 @default.
• W4285809991 cites W2029667189 @default.
• W4285809991 cites W2038583777 @default.
• W4285809991 cites W2053240727 @default.
• W4285809991 cites W2080261885 @default.
• W4285809991 cites W2093034859 @default.
• W4285809991 cites W2093914988 @default.
• W4285809991 cites W2096747776 @default.
• W4285809991 cites W2117628002 @default.
• W4285809991 cites W2132525235 @default.
• W4285809991 cites W2148284063 @default.
• W4285809991 cites W2150697053 @default.
• W4285809991 cites W2162869045 @default.
• W4285809991 cites W2169936405 @default.
• W4285809991 cites W2321334648 @default.
• W4285809991 cites W2622278115 @default.
• W4285809991 cites W2803199314 @default.
• W4285809991 cites W2808060919 @default.
• W4285809991 cites W2902928934 @default.
• W4285809991 cites W2912093143 @default.
• W4285809991 cites W2962938348 @default.
• W4285809991 cites W2982178303 @default.
• W4285809991 cites W3014163715 @default.
• W4285809991 cites W3022744074 @default.
• W4285809991 cites W3035186056 @default.
• W4285809991 cites W3093091130 @default.
• W4285809991 cites W3095287434 @default.
• W4285809991 cites W3136310145 @default.
• W4285809991 cites W3141938479 @default.
• W4285809991 cites W3158379422 @default.
• W4285809991 cites W3165699313 @default.
• W4285809991 cites W3188982918 @default.
• W4285809991 cites W3213527659 @default.
• W4285809991 doi "https://doi.org/10.1016/j.saa.2022.121650" @default.
• W4285809991 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35926285" @default.
• W4285809991 hasPublicationYear "2022" @default.
• W4285809991 type Work @default.
• W4285809991 citedByCount "12" @default.
• W4285809991 countsByYear W42858099912023 @default.
• W4285809991 crossrefType "journal-article" @default.
• W4285809991 hasAuthorship W4285809991A5020819410 @default.
• W4285809991 hasAuthorship W4285809991A5032103164 @default.
• W4285809991 hasAuthorship W4285809991A5054859377 @default.
• W4285809991 hasAuthorship W4285809991A5067608591 @default.
• W4285809991 hasAuthorship W4285809991A5077591572 @default.
• W4285809991 hasConcept C112887158 @default.
• W4285809991 hasConcept C120665830 @default.
• W4285809991 hasConcept C121332964 @default.
• W4285809991 hasConcept C139358910 @default.
• W4285809991 hasConcept C14158195 @default.
• W4285809991 hasConcept C145148216 @default.
• W4285809991 hasConcept C148869448 @default.
• W4285809991 hasConcept C178790620 @default.
• W4285809991 hasConcept C181500209 @default.
• W4285809991 hasConcept C184779094 @default.
• W4285809991 hasConcept C185592680 @default.
• W4285809991 hasConcept C192468462 @default.
• W4285809991 hasConcept C192562407 @default.
• W4285809991 hasConcept C32909587 @default.
• W4285809991 hasConcept C49040817 @default.
• W4285809991 hasConcept C71240020 @default.
• W4285809991 hasConcept C75079739 @default.
• W4285809991 hasConcept C75473681 @default.
• W4285809991 hasConcept C91881484 @default.
• W4285809991 hasConceptScore W4285809991C112887158 @default.
• W4285809991 hasConceptScore W4285809991C120665830 @default.
• W4285809991 hasConceptScore W4285809991C121332964 @default.
• W4285809991 hasConceptScore W4285809991C139358910 @default.
• W4285809991 hasConceptScore W4285809991C14158195 @default.
• W4285809991 hasConceptScore W4285809991C145148216 @default.
• W4285809991 hasConceptScore W4285809991C148869448 @default.
• W4285809991 hasConceptScore W4285809991C178790620 @default.
• W4285809991 hasConceptScore W4285809991C181500209 @default.
• W4285809991 hasConceptScore W4285809991C184779094 @default.
• W4285809991 hasConceptScore W4285809991C185592680 @default.
• W4285809991 hasConceptScore W4285809991C192468462 @default.
• W4285809991 hasConceptScore W4285809991C192562407 @default.
• W4285809991 hasConceptScore W4285809991C32909587 @default.
• W4285809991 hasConceptScore W4285809991C49040817 @default.

• next