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- W4286001830 abstract "Understanding the nature of and controlling the cation disorder in kesterite-based absorber materials remain a crucial challenge for improving their photovoltaic (PV) performances. Herein, the combination of neutron diffraction and synchrotron-based X-ray absorption techniques was implemented to investigate the relationships among cation disorder, defect concentration, overall long-range crystallographic order, and local atomic-scale structure for (AgxCu1–x)2ZnSnSe4 (ACZTSe) material. The joint Rietveld refinement technique was used to directly reveal the effect of cation substitution and quantify the concentration of defects in Ag-alloyed stoichiometric and nonstoichiometric Cu2ZnSnSe4 (CZTSe). The results showed that 10%-Ag-alloyed nonstoichiometric ACZTSe had the lowest concentration of detrimental antisite CuZn defects (∼8 × 1019 defects per cm–3), which was two times lower than pristine and five times lower than the stoichiometric compositions. Moreover, Ag incorporation maintained the concentrations of beneficial Cu vacancies (VCu) and antisite ZnCu defects to >2 × 1020 defects per cm–3. X-ray absorption measurements were performed to verify the degree of disorder through the changes in bond length and coordination number. Therefore, the incorporation of Ag into the CZTSe lattice could control the distribution of antisite defects, in the form of short- and long-range site disorder. This study paves the way to systematically understand and further improve the properties of kesterite-based materials for different energy applications." @default.
- W4286001830 created "2022-07-21" @default.
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- W4286001830 date "2022-07-20" @default.
- W4286001830 modified "2023-10-16" @default.
- W4286001830 title "Short- and Long-Range Cation Disorder in (Ag<i><sub>x</sub></i>Cu<sub>1–<i>x</i></sub>)<sub>2</sub>ZnSnSe<sub>4</sub> Kesterites" @default.
- W4286001830 cites W1508977243 @default.
- W4286001830 cites W1550228217 @default.
- W4286001830 cites W1774850859 @default.
- W4286001830 cites W1958875537 @default.
- W4286001830 cites W1966634078 @default.
- W4286001830 cites W1979583260 @default.
- W4286001830 cites W1981267556 @default.
- W4286001830 cites W1987797142 @default.
- W4286001830 cites W2004718710 @default.
- W4286001830 cites W2006045754 @default.
- W4286001830 cites W2011681169 @default.
- W4286001830 cites W2016260972 @default.
- W4286001830 cites W2021630428 @default.
- W4286001830 cites W2022097197 @default.
- W4286001830 cites W2028056984 @default.
- W4286001830 cites W2029081657 @default.
- W4286001830 cites W2032365205 @default.
- W4286001830 cites W2035608334 @default.
- W4286001830 cites W2037716102 @default.
- W4286001830 cites W2040996926 @default.
- W4286001830 cites W2041115857 @default.
- W4286001830 cites W2041297874 @default.
- W4286001830 cites W2059430749 @default.
- W4286001830 cites W2063127218 @default.
- W4286001830 cites W2069194786 @default.
- W4286001830 cites W2070227796 @default.
- W4286001830 cites W2116258136 @default.
- W4286001830 cites W2140970991 @default.
- W4286001830 cites W2142656336 @default.
- W4286001830 cites W2146825023 @default.
- W4286001830 cites W2159623292 @default.
- W4286001830 cites W2285848954 @default.
- W4286001830 cites W2331220836 @default.
- W4286001830 cites W2440644314 @default.
- W4286001830 cites W2534681016 @default.
- W4286001830 cites W2550278563 @default.
- W4286001830 cites W2560088951 @default.
- W4286001830 cites W2562157179 @default.
- W4286001830 cites W2584907598 @default.
- W4286001830 cites W2606922889 @default.
- W4286001830 cites W2607029785 @default.
- W4286001830 cites W2607817207 @default.
- W4286001830 cites W2737053422 @default.
- W4286001830 cites W2765887473 @default.
- W4286001830 cites W2766418113 @default.
- W4286001830 cites W2766556189 @default.
- W4286001830 cites W2766736183 @default.
- W4286001830 cites W2775257231 @default.
- W4286001830 cites W2776115569 @default.
- W4286001830 cites W2808107987 @default.
- W4286001830 cites W2810394859 @default.
- W4286001830 cites W2816522366 @default.
- W4286001830 cites W2819730093 @default.
- W4286001830 cites W2893420284 @default.
- W4286001830 cites W2899162252 @default.
- W4286001830 cites W2901224262 @default.
- W4286001830 cites W2924034060 @default.
- W4286001830 cites W2933676183 @default.
- W4286001830 cites W2951430805 @default.
- W4286001830 cites W2988821661 @default.
- W4286001830 cites W2989362451 @default.
- W4286001830 cites W2997626282 @default.
- W4286001830 cites W3015586579 @default.
- W4286001830 cites W3023841998 @default.
- W4286001830 cites W3028291554 @default.
- W4286001830 cites W3106735702 @default.
- W4286001830 cites W3109201334 @default.
- W4286001830 cites W3109230889 @default.
- W4286001830 cites W3153115900 @default.
- W4286001830 cites W3167947046 @default.
- W4286001830 cites W3182469330 @default.
- W4286001830 cites W3186764938 @default.
- W4286001830 cites W3208835066 @default.
- W4286001830 cites W4220689056 @default.
- W4286001830 cites W831692791 @default.
- W4286001830 cites W2976646412 @default.
- W4286001830 doi "https://doi.org/10.1021/acs.chemmater.2c01489" @default.
- W4286001830 hasPublicationYear "2022" @default.
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