FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4286008680> ?p ?o ?g. }

• W4286008680 endingPage "11786" @default.
• W4286008680 startingPage "11775" @default.
• W4286008680 abstract "Sulfur oxides from the combustion of petrol and excessive emissions of carbon dioxide (CO2) are currently the main causes of environmental pollution. Considerable interest has been paid to solving the challenge, and catalytic reactions seem to be the desired choice. Due to the high density of Lewis acid active sites, polyoxometalates are considered to be the ideal choice for these catalytic reactions. Herein, two captivating polyoxometalate-based metal–organic complexes, formulated as [Co(H2O)2DABT]2[CrMo6(OH)5O19] ({Co-CrMo6}) and [Zn(H2O)2DABT]2[CrMo6(OH)5O19] ({Zn-CrMo6}) (DABT = 3,3′-diamino-5,5′-bis(1H-1,2,4-triazole)) were successfully obtained under hydrothermal conditions. The structural analysis demonstrates that {Co-CrMo6} and {Zn-CrMo6} are isostructural with two different transition metal (Co/Zn) ions based on quadridentate Anderson-type [CrMo6(OH)5O19]4– polyanions. A fan-shaped unit of {Co-CrMo6}/{Zn-CrMo6} is linked to generate a one-dimensional (1D) ladder-like structure. Intriguingly, benefitting from rich Co centers with a suitable energy band structure, {Co-CrMo6} displays better photocatalytic activity than {Zn-CrMo6} for converting CO2 into CO, endowing the CO formation of 1935.3 μmol g–1 h–1 with high selectivity. Meanwhile, {Co-CrMo6} also exhibits a satisfactory removal rate of 99% for oxidizing dibenzothiophene at 50 °C, which suggests that {Co-CrMo6} may be utilized as a potential dual functional material with immense prospects in photocatalytic CO2 reduction and sulfur oxidation for the first time." @default.
• W4286008680 created "2022-07-21" @default.
• W4286008680 creator A5006509994 @default.
• W4286008680 creator A5030348456 @default.
• W4286008680 creator A5033939459 @default.
• W4286008680 creator A5043270885 @default.
• W4286008680 creator A5054245274 @default.
• W4286008680 creator A5060605205 @default.
• W4286008680 date "2022-07-20" @default.
• W4286008680 modified "2023-10-16" @default.
• W4286008680 title "Two 1D Anderson-Type Polyoxometalate-Based Metal–Organic Complexes as Bifunctional Heterogeneous Catalysts for CO₂ Photoreduction and Sulfur Oxidation" @default.
• W4286008680 cites W1272077656 @default.
• W4286008680 cites W1610920879 @default.
• W4286008680 cites W1897038707 @default.
• W4286008680 cites W1964552130 @default.
• W4286008680 cites W2009591453 @default.
• W4286008680 cites W2015122610 @default.
• W4286008680 cites W2076947177 @default.
• W4286008680 cites W2106149783 @default.
• W4286008680 cites W2142868818 @default.
• W4286008680 cites W2152509431 @default.
• W4286008680 cites W2154310752 @default.
• W4286008680 cites W2162942111 @default.
• W4286008680 cites W2163450343 @default.
• W4286008680 cites W2290506755 @default.
• W4286008680 cites W2297401062 @default.
• W4286008680 cites W2308137288 @default.
• W4286008680 cites W2324073065 @default.
• W4286008680 cites W2502288548 @default.
• W4286008680 cites W2529516308 @default.
• W4286008680 cites W2560782857 @default.
• W4286008680 cites W2566456487 @default.
• W4286008680 cites W2606670976 @default.
• W4286008680 cites W2609277956 @default.
• W4286008680 cites W2771345288 @default.
• W4286008680 cites W2791702310 @default.
• W4286008680 cites W2795479730 @default.
• W4286008680 cites W2897279823 @default.
• W4286008680 cites W2904513480 @default.
• W4286008680 cites W2908934650 @default.
• W4286008680 cites W2912983862 @default.
• W4286008680 cites W2922127343 @default.
• W4286008680 cites W2944445042 @default.
• W4286008680 cites W2955688930 @default.
• W4286008680 cites W2964440511 @default.
• W4286008680 cites W2968546578 @default.
• W4286008680 cites W2984006341 @default.
• W4286008680 cites W2984358224 @default.
• W4286008680 cites W3005444397 @default.
• W4286008680 cites W3022628923 @default.
• W4286008680 cites W3031279733 @default.
• W4286008680 cites W3047711588 @default.
• W4286008680 cites W3136122980 @default.
• W4286008680 cites W3136325722 @default.
• W4286008680 cites W3139461276 @default.
• W4286008680 cites W3158678700 @default.
• W4286008680 cites W3162382695 @default.
• W4286008680 cites W3164904761 @default.
• W4286008680 cites W3176419561 @default.
• W4286008680 cites W3197257178 @default.
• W4286008680 cites W3213097595 @default.
• W4286008680 cites W4200271600 @default.
• W4286008680 cites W4205739454 @default.
• W4286008680 cites W4206687824 @default.
• W4286008680 cites W4206691217 @default.
• W4286008680 cites W4239370604 @default.
• W4286008680 cites W4240514390 @default.
• W4286008680 cites W4285154908 @default.
• W4286008680 doi "https://doi.org/10.1021/acs.inorgchem.2c01497" @default.
• W4286008680 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35858285" @default.
• W4286008680 hasPublicationYear "2022" @default.
• W4286008680 type Work @default.
• W4286008680 citedByCount "6" @default.
• W4286008680 countsByYear W42860086802022 @default.
• W4286008680 countsByYear W42860086802023 @default.
• W4286008680 crossrefType "journal-article" @default.
• W4286008680 hasAuthorship W4286008680A5006509994 @default.
• W4286008680 hasAuthorship W4286008680A5030348456 @default.
• W4286008680 hasAuthorship W4286008680A5033939459 @default.
• W4286008680 hasAuthorship W4286008680A5043270885 @default.
• W4286008680 hasAuthorship W4286008680A5054245274 @default.
• W4286008680 hasAuthorship W4286008680A5060605205 @default.
• W4286008680 hasConcept C106773901 @default.
• W4286008680 hasConcept C115624301 @default.
• W4286008680 hasConcept C161790260 @default.
• W4286008680 hasConcept C163638829 @default.
• W4286008680 hasConcept C178790620 @default.
• W4286008680 hasConcept C179104552 @default.
• W4286008680 hasConcept C185592680 @default.
• W4286008680 hasConcept C205188671 @default.
• W4286008680 hasConcept C2777498215 @default.
• W4286008680 hasConcept C2780443040 @default.
• W4286008680 hasConcept C2780596425 @default.
• W4286008680 hasConcept C518881349 @default.
• W4286008680 hasConcept C55904794 @default.
• W4286008680 hasConcept C65165184 @default.
• W4286008680 hasConceptScore W4286008680C106773901 @default.
• W4286008680 hasConceptScore W4286008680C115624301 @default.

• next