FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4286267550> ?p ?o ?g. }

• W4286267550 endingPage "119894" @default.
• W4286267550 startingPage "119894" @default.
• W4286267550 abstract "Understanding the confinement-induced phase behavior of fluids stored in nanometer-sized pores of solid materials is paramount in various science and engineering applications. Experimental findings describing fluid phase behavior in confinement are often used to develop the efficient and accurate equation of state models that can then provide a cost-effective approach to predict such information for different applications. However, there is a scarcity of experimental data in the literature that can offer insights into the confinement effects under varying conditions. The present work endeavors to provide new experimental data on the effects of pore size and temperature on the confined phase behavior of two chemical species (n-Butane and iso-Butane) and thereby improve the current understanding of the impact of these parameters on capillary condensation, evaporation, and hysteresis. We use a patented gravimetric apparatus that was upgraded in this study by the development and incorporation of advanced automated data acquisition modules. The automation module improved the data collection quality by fine-tuning the fluid injection and withdrawal processes which significantly enhanced the accuracy and precision of the measured isotherms. The capillary condensation and evaporation processes were then studied using a nanoporous material known as Mobil Composition of Matter No. 41 (MCM-41), a mesoporous medium with well-defined pore shape and sizes. The isotherms were obtained for a wide range of temperatures (−7, −3, 0, 7, 8.7, 17, and 27 °C) and using MCM-41 with various pore sizes (60, 80, 100, and 120 Å). The accuracy of the measurements was validated against the phase behavior data of bulk n-Butane and iso-Butane reported by the National Institute of Standards and Technology (NIST). The capillary condensation pressures obtained from the isotherms for different pore sizes agreed with the trends reported in the literature. The results show that the capillary condensation pressures of the fluids increase with the pore size and temperature. The measured isotherms and capillary condensation pressures provide new data sets on the condensation characteristics of n-Butane and iso-Butane. They are expected to contribute to the fundamental understanding of the confined phase behavior of hydrocarbons and thereby advance the development of improved equations of state models that can accurately describe the phase behavior of fluids in nanoporous media. PC-SAFT/Laplace EOS was used to model the phase behavior of the fluids under confinement. The predictions from the PC-SAFT model agree with previous data therefore the results from this study can be integrated into building more robust models." @default.
• W4286267550 created "2022-07-21" @default.
• W4286267550 creator A5038190724 @default.
• W4286267550 creator A5062159537 @default.
• W4286267550 creator A5063558387 @default.
• W4286267550 date "2022-10-01" @default.
• W4286267550 modified "2023-09-26" @default.
• W4286267550 title "Capillary condensation and evaporation of n-butane and iso-butane in nanoporous media: Experimental study of the effects of pore size and temperature using an automated gravimetric apparatus" @default.
• W4286267550 cites W1478861898 @default.
• W4286267550 cites W1588163064 @default.
• W4286267550 cites W1988206963 @default.
• W4286267550 cites W1989632172 @default.
• W4286267550 cites W1989901395 @default.
• W4286267550 cites W2005901007 @default.
• W4286267550 cites W2025865501 @default.
• W4286267550 cites W2031556656 @default.
• W4286267550 cites W2036281599 @default.
• W4286267550 cites W2044742960 @default.
• W4286267550 cites W2045044994 @default.
• W4286267550 cites W2046430541 @default.
• W4286267550 cites W2052658007 @default.
• W4286267550 cites W2073601842 @default.
• W4286267550 cites W2085237940 @default.
• W4286267550 cites W2090187365 @default.
• W4286267550 cites W2095062440 @default.
• W4286267550 cites W2101146408 @default.
• W4286267550 cites W2312510616 @default.
• W4286267550 cites W2504958700 @default.
• W4286267550 cites W2784770925 @default.
• W4286267550 cites W2796006250 @default.
• W4286267550 cites W2884610423 @default.
• W4286267550 cites W2966344092 @default.
• W4286267550 cites W3036061225 @default.
• W4286267550 cites W3122467524 @default.
• W4286267550 cites W3134217771 @default.
• W4286267550 cites W3168249455 @default.
• W4286267550 cites W3200937068 @default.
• W4286267550 cites W3214077210 @default.
• W4286267550 doi "https://doi.org/10.1016/j.molliq.2022.119894" @default.
• W4286267550 hasPublicationYear "2022" @default.
• W4286267550 type Work @default.
• W4286267550 citedByCount "1" @default.
• W4286267550 countsByYear W42862675502023 @default.
• W4286267550 crossrefType "journal-article" @default.
• W4286267550 hasAuthorship W4286267550A5038190724 @default.
• W4286267550 hasAuthorship W4286267550A5062159537 @default.
• W4286267550 hasAuthorship W4286267550A5063558387 @default.
• W4286267550 hasConcept C105569014 @default.
• W4286267550 hasConcept C121332964 @default.
• W4286267550 hasConcept C127413603 @default.
• W4286267550 hasConcept C150394285 @default.
• W4286267550 hasConcept C159985019 @default.
• W4286267550 hasConcept C161790260 @default.
• W4286267550 hasConcept C171250308 @default.
• W4286267550 hasConcept C178790620 @default.
• W4286267550 hasConcept C185498141 @default.
• W4286267550 hasConcept C185592680 @default.
• W4286267550 hasConcept C192562407 @default.
• W4286267550 hasConcept C196806460 @default.
• W4286267550 hasConcept C200093464 @default.
• W4286267550 hasConcept C21880701 @default.
• W4286267550 hasConcept C2778717364 @default.
• W4286267550 hasConcept C42360764 @default.
• W4286267550 hasConcept C48940184 @default.
• W4286267550 hasConcept C61441594 @default.
• W4286267550 hasConcept C6648577 @default.
• W4286267550 hasConcept C82776694 @default.
• W4286267550 hasConcept C84351421 @default.
• W4286267550 hasConcept C86381522 @default.
• W4286267550 hasConcept C96278889 @default.
• W4286267550 hasConcept C97355855 @default.
• W4286267550 hasConceptScore W4286267550C105569014 @default.
• W4286267550 hasConceptScore W4286267550C121332964 @default.
• W4286267550 hasConceptScore W4286267550C127413603 @default.
• W4286267550 hasConceptScore W4286267550C150394285 @default.
• W4286267550 hasConceptScore W4286267550C159985019 @default.
• W4286267550 hasConceptScore W4286267550C161790260 @default.
• W4286267550 hasConceptScore W4286267550C171250308 @default.
• W4286267550 hasConceptScore W4286267550C178790620 @default.
• W4286267550 hasConceptScore W4286267550C185498141 @default.
• W4286267550 hasConceptScore W4286267550C185592680 @default.
• W4286267550 hasConceptScore W4286267550C192562407 @default.
• W4286267550 hasConceptScore W4286267550C196806460 @default.
• W4286267550 hasConceptScore W4286267550C200093464 @default.
• W4286267550 hasConceptScore W4286267550C21880701 @default.
• W4286267550 hasConceptScore W4286267550C2778717364 @default.
• W4286267550 hasConceptScore W4286267550C42360764 @default.
• W4286267550 hasConceptScore W4286267550C48940184 @default.
• W4286267550 hasConceptScore W4286267550C61441594 @default.
• W4286267550 hasConceptScore W4286267550C6648577 @default.
• W4286267550 hasConceptScore W4286267550C82776694 @default.
• W4286267550 hasConceptScore W4286267550C84351421 @default.
• W4286267550 hasConceptScore W4286267550C86381522 @default.
• W4286267550 hasConceptScore W4286267550C96278889 @default.
• W4286267550 hasConceptScore W4286267550C97355855 @default.
• W4286267550 hasFunder F4320307925 @default.
• W4286267550 hasFunder F4320310258 @default.
• W4286267550 hasLocation W42862675501 @default.

• next