Matches in SemOpenAlex for { <https://semopenalex.org/work/W4286435170> ?p ?o ?g. }
- W4286435170 endingPage "116050" @default.
- W4286435170 startingPage "116050" @default.
- W4286435170 abstract "This paper describes the synthesis, structural and spectroscopic characterizations of two new trinuclear iron(III) complexes: [Fe3(LS)(μ –OH)2(μ -OAc)2]ClO4 (CS) and [Fe3(LSe)(μ –OH)2(μ -OAc)2]ClO4 (CSe) with two new phenol-based ligands containing chalcogen atoms (S or Se) in pendant arms. Both iron complexes were characterized using the following techniques: X-ray crystallography, elemental analysis, IR, Mossbauer and UV–vis spectroscopies, conductimetric analysis and mass spectrometry. The crystal structures of the complexes reveal that their coordination center is formed by three linearly arranged iron atoms, joined by μ -hydroxo, μ -phenoxo and μ -acetato bridges. The hydrolytic activity in the phosphate diester cleavage of CSe and CS was investigated using 2,4-BDNPP as a substrate, and applying the Michaelis-Menten approach, giving the kinetic parameters (CSe/CS): kcat (s−1) = 3.81 × 10-3/2.32 × 10-3 and a catalytic efficiency of E = kcat/ KM, (L/mol s−1) = 1.83/3.18. The complexes and ligands also showed antioxidant activity." @default.
- W4286435170 created "2022-07-22" @default.
- W4286435170 creator A5008227123 @default.
- W4286435170 creator A5009605694 @default.
- W4286435170 creator A5010796656 @default.
- W4286435170 creator A5022190206 @default.
- W4286435170 creator A5035934799 @default.
- W4286435170 creator A5052077381 @default.
- W4286435170 creator A5056700581 @default.
- W4286435170 creator A5089175587 @default.
- W4286435170 creator A5091662225 @default.
- W4286435170 date "2022-10-01" @default.
- W4286435170 modified "2023-09-23" @default.
- W4286435170 title "Synthesis, structure and properties of new triiron(III) complexes: Phosphodiester cleavage and antioxidant activity" @default.
- W4286435170 cites W133692741 @default.
- W4286435170 cites W1423887221 @default.
- W4286435170 cites W1931308953 @default.
- W4286435170 cites W1967244854 @default.
- W4286435170 cites W1972060131 @default.
- W4286435170 cites W1975675322 @default.
- W4286435170 cites W1978160165 @default.
- W4286435170 cites W1990213423 @default.
- W4286435170 cites W1990244829 @default.
- W4286435170 cites W1998722626 @default.
- W4286435170 cites W2004352246 @default.
- W4286435170 cites W2012871574 @default.
- W4286435170 cites W2015470613 @default.
- W4286435170 cites W2019237634 @default.
- W4286435170 cites W2023838843 @default.
- W4286435170 cites W2031337819 @default.
- W4286435170 cites W2043123654 @default.
- W4286435170 cites W2044513975 @default.
- W4286435170 cites W2046412198 @default.
- W4286435170 cites W2047570710 @default.
- W4286435170 cites W2053065115 @default.
- W4286435170 cites W2092698645 @default.
- W4286435170 cites W2094105531 @default.
- W4286435170 cites W2109868674 @default.
- W4286435170 cites W2147721582 @default.
- W4286435170 cites W2152907771 @default.
- W4286435170 cites W2170996876 @default.
- W4286435170 cites W2331731218 @default.
- W4286435170 cites W2514041565 @default.
- W4286435170 cites W2740956562 @default.
- W4286435170 cites W2767557713 @default.
- W4286435170 cites W2771391032 @default.
- W4286435170 cites W2783791170 @default.
- W4286435170 cites W2791395071 @default.
- W4286435170 cites W2802600044 @default.
- W4286435170 cites W2810545410 @default.
- W4286435170 cites W2888479710 @default.
- W4286435170 cites W2911741207 @default.
- W4286435170 cites W2924834281 @default.
- W4286435170 cites W2937822749 @default.
- W4286435170 cites W2956071080 @default.
- W4286435170 cites W3004885960 @default.
- W4286435170 cites W3011686755 @default.
- W4286435170 cites W3013361005 @default.
- W4286435170 cites W3019040904 @default.
- W4286435170 cites W3046860254 @default.
- W4286435170 cites W3129969067 @default.
- W4286435170 cites W3133762795 @default.
- W4286435170 cites W3154080610 @default.
- W4286435170 cites W3185723425 @default.
- W4286435170 cites W4251754471 @default.
- W4286435170 doi "https://doi.org/10.1016/j.poly.2022.116050" @default.
- W4286435170 hasPublicationYear "2022" @default.
- W4286435170 type Work @default.
- W4286435170 citedByCount "1" @default.
- W4286435170 countsByYear W42864351702023 @default.
- W4286435170 crossrefType "journal-article" @default.
- W4286435170 hasAuthorship W4286435170A5008227123 @default.
- W4286435170 hasAuthorship W4286435170A5009605694 @default.
- W4286435170 hasAuthorship W4286435170A5010796656 @default.
- W4286435170 hasAuthorship W4286435170A5022190206 @default.
- W4286435170 hasAuthorship W4286435170A5035934799 @default.
- W4286435170 hasAuthorship W4286435170A5052077381 @default.
- W4286435170 hasAuthorship W4286435170A5056700581 @default.
- W4286435170 hasAuthorship W4286435170A5089175587 @default.
- W4286435170 hasAuthorship W4286435170A5091662225 @default.
- W4286435170 hasConcept C104317684 @default.
- W4286435170 hasConcept C115624301 @default.
- W4286435170 hasConcept C127413603 @default.
- W4286435170 hasConcept C158733187 @default.
- W4286435170 hasConcept C161790260 @default.
- W4286435170 hasConcept C175156509 @default.
- W4286435170 hasConcept C178790620 @default.
- W4286435170 hasConcept C185592680 @default.
- W4286435170 hasConcept C187320778 @default.
- W4286435170 hasConcept C2777702071 @default.
- W4286435170 hasConcept C38441620 @default.
- W4286435170 hasConcept C41183919 @default.
- W4286435170 hasConcept C43369102 @default.
- W4286435170 hasConcept C55493867 @default.
- W4286435170 hasConcept C56856141 @default.
- W4286435170 hasConcept C67705224 @default.
- W4286435170 hasConcept C70854507 @default.
- W4286435170 hasConcept C71240020 @default.