FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4286484189> ?p ?o ?g. }

• W4286484189 endingPage "107390" @default.
• W4286484189 startingPage "107390" @default.
• W4286484189 abstract "The softening and foaming of lignin during pyrolysis are the main obstacles to the scale-up of lignin pyrolysis systems. In this study, the mechanism of borate crosslinking on lignin softening and pyrolysis process was investigated by combining in-situ physical and chemical techniques. First, the mobile protons and visco-elastic modulus during lignin pyrolysis were quantitatively analyzed by in-situ high temperature 1H NMR and rheology. It was found that the maximum content of mobile protons during the pyrolysis of raw lignin is around 90%. Hydroxyl crosslinking greatly inhibits the formation of mobile protons. The raw lignin produces a soft material from about 150 °C and starts to form a more rigid material from 200 °C. At 210 °C ~ 330 °C, mobile liquid-like intermediates are entrapped in the rigid char, forming “cavities”. With the addition of boron, the viscoelasticity tends to be stable and mainly elastic. Then, in-situ diffuse reflectance infrared Fourier transform spectroscopy and single photoionization time-of-flight mass spectrometry were used to characterize the evolution of functional groups and volatiles. It was found that the shielding of hydroxyl groups by borate inhibits the decomposition of lignin but improves the selectivity to phenols, and more oxygenated groups remain in the char." @default.
• W4286484189 created "2022-07-22" @default.
• W4286484189 creator A5007450053 @default.
• W4286484189 creator A5014652467 @default.
• W4286484189 creator A5018397055 @default.
• W4286484189 creator A5024934519 @default.
• W4286484189 creator A5033237840 @default.
• W4286484189 creator A5049614897 @default.
• W4286484189 creator A5067671100 @default.
• W4286484189 creator A5075619789 @default.
• W4286484189 creator A5085358803 @default.
• W4286484189 date "2022-11-01" @default.
• W4286484189 modified "2023-10-09" @default.
• W4286484189 title "Impacts of the hydroxyls crosslinking on lignin softening and pyrolysis via in situ 1H NMR, rheology, DRIFT and SPI-MS" @default.
• W4286484189 cites W1926090992 @default.
• W4286484189 cites W1993429758 @default.
• W4286484189 cites W2052751604 @default.
• W4286484189 cites W2083802424 @default.
• W4286484189 cites W2105352289 @default.
• W4286484189 cites W2332791109 @default.
• W4286484189 cites W2643703840 @default.
• W4286484189 cites W2773226674 @default.
• W4286484189 cites W2792676415 @default.
• W4286484189 cites W2884040964 @default.
• W4286484189 cites W2888808363 @default.
• W4286484189 cites W2938660842 @default.
• W4286484189 cites W2956853036 @default.
• W4286484189 cites W2966794499 @default.
• W4286484189 cites W2991574836 @default.
• W4286484189 cites W2997642714 @default.
• W4286484189 cites W3081359934 @default.
• W4286484189 cites W3081475340 @default.
• W4286484189 cites W3108588388 @default.
• W4286484189 cites W3169923317 @default.
• W4286484189 cites W3196096550 @default.
• W4286484189 cites W3197756528 @default.
• W4286484189 cites W4212979446 @default.
• W4286484189 doi "https://doi.org/10.1016/j.fuproc.2022.107390" @default.
• W4286484189 hasPublicationYear "2022" @default.
• W4286484189 type Work @default.
• W4286484189 citedByCount "2" @default.
• W4286484189 countsByYear W42864841892022 @default.
• W4286484189 countsByYear W42864841892023 @default.
• W4286484189 crossrefType "journal-article" @default.
• W4286484189 hasAuthorship W4286484189A5007450053 @default.
• W4286484189 hasAuthorship W4286484189A5014652467 @default.
• W4286484189 hasAuthorship W4286484189A5018397055 @default.
• W4286484189 hasAuthorship W4286484189A5024934519 @default.
• W4286484189 hasAuthorship W4286484189A5033237840 @default.
• W4286484189 hasAuthorship W4286484189A5049614897 @default.
• W4286484189 hasAuthorship W4286484189A5067671100 @default.
• W4286484189 hasAuthorship W4286484189A5075619789 @default.
• W4286484189 hasAuthorship W4286484189A5085358803 @default.
• W4286484189 hasBestOaLocation W42864841892 @default.
• W4286484189 hasConcept C127413603 @default.
• W4286484189 hasConcept C159985019 @default.
• W4286484189 hasConcept C178790620 @default.
• W4286484189 hasConcept C185592680 @default.
• W4286484189 hasConcept C192562407 @default.
• W4286484189 hasConcept C200990466 @default.
• W4286484189 hasConcept C2779970684 @default.
• W4286484189 hasConcept C2781052789 @default.
• W4286484189 hasConcept C2781098093 @default.
• W4286484189 hasConcept C36759035 @default.
• W4286484189 hasConcept C42360764 @default.
• W4286484189 hasConcept C501308230 @default.
• W4286484189 hasConcept C83608634 @default.
• W4286484189 hasConceptScore W4286484189C127413603 @default.
• W4286484189 hasConceptScore W4286484189C159985019 @default.
• W4286484189 hasConceptScore W4286484189C178790620 @default.
• W4286484189 hasConceptScore W4286484189C185592680 @default.
• W4286484189 hasConceptScore W4286484189C192562407 @default.
• W4286484189 hasConceptScore W4286484189C200990466 @default.
• W4286484189 hasConceptScore W4286484189C2779970684 @default.
• W4286484189 hasConceptScore W4286484189C2781052789 @default.
• W4286484189 hasConceptScore W4286484189C2781098093 @default.
• W4286484189 hasConceptScore W4286484189C36759035 @default.
• W4286484189 hasConceptScore W4286484189C42360764 @default.
• W4286484189 hasConceptScore W4286484189C501308230 @default.
• W4286484189 hasConceptScore W4286484189C83608634 @default.
• W4286484189 hasFunder F4320321001 @default.
• W4286484189 hasFunder F4320322725 @default.
• W4286484189 hasLocation W42864841891 @default.
• W4286484189 hasLocation W42864841892 @default.
• W4286484189 hasLocation W42864841893 @default.
• W4286484189 hasOpenAccess W4286484189 @default.
• W4286484189 hasPrimaryLocation W42864841891 @default.
• W4286484189 hasRelatedWork W1980046758 @default.
• W4286484189 hasRelatedWork W2063807941 @default.
• W4286484189 hasRelatedWork W2066285040 @default.
• W4286484189 hasRelatedWork W2084800349 @default.
• W4286484189 hasRelatedWork W2285265924 @default.
• W4286484189 hasRelatedWork W2585146776 @default.
• W4286484189 hasRelatedWork W2980327521 @default.
• W4286484189 hasRelatedWork W3137747762 @default.
• W4286484189 hasRelatedWork W4224236492 @default.
• W4286484189 hasRelatedWork W4248342369 @default.
• W4286484189 hasVolume "236" @default.

• next