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- W4286501677 abstract "Vitamin E consists of a group of compounds including α- β- γ- and δ-tocopherols and α- β- γ- and δ-tocotrienols, containing the chroman-6-ol system. The recognition of the structural and dynamic properties of this system, present in all vitamers, seems to be important for the full explanation of the mechanism of the biological activity of vitamin E. This paper presents results of the structural analysis of the chosen 6-chromanyl ethereal derivatives using experimental (13 C NMR-in solution and solid state, as well as variable temperature experiments; single crystal X-ray diffraction) and theoretical (DFT) methods. For one of the studied compounds, 2,2,5,7,8-pentamethyl-6-((tetrahydro-2H-pyran-2-yl)oxy) chroman, the splitting of some signals was observed in the 13C dynamic NMR spectra. This observation was explained by the application of a conformational analysis and subsequent DFT optimization, followed by the calculation of NMR properties." @default.
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- W4286501677 date "2022-07-20" @default.
- W4286501677 modified "2023-09-26" @default.
- W4286501677 title "13C CP MAS NMR and DFT Studies of 6-Chromanyl Ethereal Derivatives" @default.
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- W4286501677 doi "https://doi.org/10.3390/molecules27144630" @default.
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