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- W4286511227 abstract "Solid ceramic fuel cells (SCFCs) are considered to be an irreplaceable energy conversion device in the future because of their high energy−conversion efficiency, non−combustion operation, and low−carbon emission. However, the commercialization of SCFCs is still limited by their higher operating temperatures (> 700 °C). In view of this challenge, we use two−dimensional silica derived from natural clay mineral vermiculite as the source of silicon to prepare Zn 2 SiO 4 , and then incorporate it with the ZnO material to design Zn 2 SiO 4 –ZnO heterogeneous semiconductor structure to realize fast carrier transport in electrolyte. We detected the electrochemical properties of Zn 2 SiO 4 –ZnO composite fuel cells at different molar ratios detail. The fabricated fuel cells demonstrate the best performance with power density of 692 mW cm −2 and a higher ionic conductivity of 0.23 S cm −1 for the fuel cell using 2Zn 2 SiO 4 –8ZnO composite as the electrolyte, which represents approximately 75% improvement comparing with pure ZnO fuel cell. Considering the rich reservation and ultra−low−cost of natural minerals, this work also provides an approach to develop nanocomposite energy materials derived from natural minerals for the application of green energy conversion." @default.
- W4286511227 created "2022-07-22" @default.
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- W4286511227 date "2022-11-01" @default.
- W4286511227 modified "2023-09-29" @default.
- W4286511227 title "Interfacial ionic conductivity of two−dimensional heterogeneous semiconductor ZnO composited with Zn2SiO4 derived from natural clay mineral vermiculite" @default.
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- W4286511227 doi "https://doi.org/10.1016/j.ceramint.2022.07.189" @default.
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