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- W4286540057 abstract "The presence of a permethylated α-cyclodextrin (α-CD) cavity in a chelating P,N ligand promotes exclusive formation of 1 : 1 ligand/metal complexes. In MX2 complexes, one of the two halido ligands is forced to reside inside the CD hollow while the second one is pointing outside. Unlike its cavity-free analogue, a Ni(II) complex of the CD ligand is a highly selective precatalyst for ethylene dimerisation (96% C4 selectivity with up to 95% of 1-butene within the C4 fraction)." @default.
- W4286540057 created "2022-07-22" @default.
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- W4286540057 date "2022-01-01" @default.
- W4286540057 modified "2023-09-26" @default.
- W4286540057 title "A cavity-shaped <i>cis</i>-chelating P,N ligand for highly selective nickel-catalysed ethylene dimerisation" @default.
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- W4286540057 doi "https://doi.org/10.1039/d2dt01553f" @default.
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