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- W4286567615 endingPage "121775" @default.
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- W4286567615 abstract "The ZSM-11 zeolite has been revealed as an undervalued catalyst for the catalytic fast pyrolysis (CFP) of biomass to produce hydrocarbon-rich bio-oil. However, the importance of hierarchical ZSM-11 in bio-oil production is still unknown. Herein, a series of ZSM-11 with varied morphologies, acidities, and secondary mesopores were synthesized and tested as catalysts in the CFP of maize straw. For the morphology series, ZSM-11 with separate nanorods ( Nano -ZSM-11 ) or aggregated nanosized single-crystal ( NS - ZSM - 11 ) performed better in bio-oil production than microsized Micro -ZSM-11 . Regarding the NS -ZSM-11 series, optimal acidity facilitated the deoxygenation of biomass vapor, while introduced intracrystal mesopores tended to improve bio-oil yield. NS-ZSM-11 (20)-0.3 possessing both adequate acidity and coupling inter/intracrystal mesopores led to a satisfactory bio-oil yield (23.6 wt%) and hydrocarbon selectivity (63.6 area%), which were 1.1 and 1.3 times those for Nano -ZSM-11 (bio-oil yield: 22.0 wt%; hydrocarbon selectivity: 47.8 area%), respectively. NS-ZSM-11 (20)-0.3 also showed excellent reusability in regeneration-pyrolysis cycles. • ZSM-11 with varied morphologies, acidity, and mesopores were tested for biomass CFP. • ZSM-11 with a separate or assembled nanorod morphology preferred bio-oil production. • An optimal NS -ZSM-11 acidity facilitated the deoxygenation of biomass vapors. • The intra-crystal mesopores in NS -ZSM-11 tended to improve bio-oil yield. • NS-ZSM-11 (20)‐0.3 with a coupled inter-/intra-crystal mesopores performed best." @default.
- W4286567615 created "2022-07-22" @default.
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- W4286567615 date "2022-11-01" @default.
- W4286567615 modified "2023-10-09" @default.
- W4286567615 title "Enhanced production of hydrocarbons from the catalytic pyrolysis of maize straw over hierarchical ZSM-11 zeolites" @default.
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- W4286567615 doi "https://doi.org/10.1016/j.apcatb.2022.121775" @default.
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