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• W4286615271 abstract "Abstract The average and local structures of solid solutions of (1 – x )BiFeO 3 – x BaTiO 3 were investigated. At room temperature, pseudo-cubic phases appear in BaTiO 3 compositions with x values ranging from 0.3 to 0.7. The ferroelectricity was not lost even in the cubic structure with the highest ferroelectricity observed at x = 0.3. We used a pair distribution function and an X-ray absorption fine structure to perform a structural analysis to determine the source of this ferroelectricity. These solid solutions’ local structures were consistent with the pure limits of BiFeO 3 and BaTiO 3 , respectively, but when the composition of BaTiO 3 was 0.3, a structure peculiar to the structural boundary in the solid solutions appeared. We discovered that the structure had the greatest randomness around this composition by performing a model fit of this local structure. Local structure changes to improve nanoscale dipole interactions while maintaining the ferroelectric long-range order structure. As a result, the domain size grows and the ferroelectricity improves." @default.
• W4286615271 created "2022-07-23" @default.
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• W4286615271 date "2022-08-18" @default.
• W4286615271 modified "2023-09-26" @default.
• W4286615271 title "Local structure analysis of BiFeO₃-BaTiO₃ solid solutions" @default.
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• W4286615271 doi "https://doi.org/10.35848/1347-4065/ac835d" @default.
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