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- W4287180469 abstract "Capping ligands are crucial to synthesize colloidal nanoparticles with novel functional properties. However, the interaction between capping ligands and their interaction with the crystallographic surfaces of nanoparticles during colloidal synthesis remains a great mystery, due to the lack of direct imaging techniques. In this study, atom probe tomography was adopted to investigate the three-dimensional atomic-scale distribution of two of the most common types of these ligands, cetrimonium and halide (Br and Cl) ions, on Pd nanoparticles. The results, validated using the density functional theory, demonstrated that the Br anions adsorbed on the nanoparticle surfaces promote the adsorption of the cetrimonium cations through electrostatic interactions, stabilizing the Pd {111} facets." @default.
- W4287180469 created "2022-07-25" @default.
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- W4287180469 date "2021-05-18" @default.
- W4287180469 modified "2023-09-24" @default.
- W4287180469 title "Three-dimensional Atomic Mapping of Ligands on Nanoparticles" @default.
- W4287180469 hasPublicationYear "2021" @default.
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