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• W4287448064 startingPage "12190" @default.
• W4287448064 abstract "It is a significant challenge to construct chiral metal–organic frameworks (CMOFs) by developing a facile and green preparation strategy. In this work, CMOFs were first synthesized via a mechanochemical process by combining a truncated mixed ligand strategy and defect engineering theory. The simple, green, and rapid construction strategy could solvent-freely harvest gram-scale CMOFs with a hierarchical micro/mesoporous structure. The as-synthesized CMOFs were evaluated by Aldol asymmetric catalysis and exhibited excellent catalytic performance (conversion was up to 97.1%, the ee value was 44.3%, and the activity was still good after 5 cycles)." @default.
• W4287448064 created "2022-07-25" @default.
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• W4287448064 date "2022-07-25" @default.
• W4287448064 modified "2023-10-02" @default.
• W4287448064 title "Green and Large-Scale Preparation of Chiral Metal–Organic Frameworks via Mechanochemistry" @default.
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• W4287448064 doi "https://doi.org/10.1021/acs.inorgchem.2c01261" @default.
• W4287448064 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35876745" @default.
• W4287448064 hasPublicationYear "2022" @default.
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