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- W4287958591 abstract "A chiral phosphoric acids catalyzed regio- and enantioselective 1,10-conjugate addition of 2-arylindoles to alkynyl indole imine methides formed in situ from α-(6-indolyl)propargylic alcohols has been developed. With the established system, organocatalytic asymmetric 3-allenylation of indoles was realized, affording a broad scope of axially chiral tetrasubstituted allenes bearing two indole motifs in high yields with stereoselectivities. Importantly, the organocatalytic remote stereocontrolled strategy disclosed the asymmetric 3-allenylation of indoles via 1,10-conjugate addition for the first time." @default.
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- W4287958591 date "2022-08-08" @default.
- W4287958591 modified "2023-10-17" @default.
- W4287958591 title "Organocatalytic Asymmetric 3‐Allenylation of Indoles via Remote Stereocontrolled 1,10‐Additions of Alkynyl Indole Imine Methides" @default.
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- W4287958591 doi "https://doi.org/10.1002/ajoc.202200399" @default.
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