Matches in SemOpenAlex for { <https://semopenalex.org/work/W4287965010> ?p ?o ?g. }
- W4287965010 endingPage "5781" @default.
- W4287965010 startingPage "5770" @default.
- W4287965010 abstract "Light-responsive particle-stabilised (Pickering) emulsions can in principle be selectively emulsified/demulsified on-demand through the remote application of light. However, despite their wide-ranging potential in applications such as drug delivery and biphasic catalysis, their rational design is extremely challenging and there are very few examples to date. Herein, we investigate a model system based on silica particles functionalised with azobenzene photoswitches to understand the key factors that determine the characteristics of light-responsive Pickering emulsions. The particle hydrophobicity is tuned through judicious variation of the spacer length used to graft the chromophores to the surface, the grafting density, and irradiation to induce trans-cis photoisomerisation. For select emulsions, and for the first time, a reversible transition between emulsified water-in-oil droplets and demulsified water and oil phases is observed with the application of either UV or blue light, which can be repeatedly cycled. A combination of surface energy analysis and optical microscopy is shown to be useful in predicting the stability, and expected light-response, of a given emulsion. Using the observed trends, a set of design rules are presented which will help facilitate the rational design, and therefore, more widespread application of light-responsive Pickering emulsions." @default.
- W4287965010 created "2022-07-26" @default.
- W4287965010 creator A5036235720 @default.
- W4287965010 creator A5078767077 @default.
- W4287965010 date "2022-01-01" @default.
- W4287965010 modified "2023-09-30" @default.
- W4287965010 title "Light-responsive Pickering emulsions based on azobenzene-modified particles" @default.
- W4287965010 cites W1621083205 @default.
- W4287965010 cites W1968282888 @default.
- W4287965010 cites W1975117973 @default.
- W4287965010 cites W1982074883 @default.
- W4287965010 cites W1999032126 @default.
- W4287965010 cites W2011393168 @default.
- W4287965010 cites W2017971562 @default.
- W4287965010 cites W2024977515 @default.
- W4287965010 cites W2043184909 @default.
- W4287965010 cites W2045064685 @default.
- W4287965010 cites W2052407823 @default.
- W4287965010 cites W2053865219 @default.
- W4287965010 cites W2055976008 @default.
- W4287965010 cites W2062548067 @default.
- W4287965010 cites W2064403993 @default.
- W4287965010 cites W2074067370 @default.
- W4287965010 cites W2084856161 @default.
- W4287965010 cites W2089277729 @default.
- W4287965010 cites W2090357758 @default.
- W4287965010 cites W2103753962 @default.
- W4287965010 cites W2113788599 @default.
- W4287965010 cites W2147831306 @default.
- W4287965010 cites W2155478020 @default.
- W4287965010 cites W2158047084 @default.
- W4287965010 cites W2159426355 @default.
- W4287965010 cites W2256853690 @default.
- W4287965010 cites W2316133297 @default.
- W4287965010 cites W2318923993 @default.
- W4287965010 cites W2483066629 @default.
- W4287965010 cites W2485638807 @default.
- W4287965010 cites W2494702451 @default.
- W4287965010 cites W2495428760 @default.
- W4287965010 cites W2520236143 @default.
- W4287965010 cites W2522133315 @default.
- W4287965010 cites W2588478233 @default.
- W4287965010 cites W2735357974 @default.
- W4287965010 cites W2788165378 @default.
- W4287965010 cites W2792071113 @default.
- W4287965010 cites W2892616597 @default.
- W4287965010 cites W2900772700 @default.
- W4287965010 cites W2907679453 @default.
- W4287965010 cites W2914845267 @default.
- W4287965010 cites W2954552964 @default.
- W4287965010 cites W2956840577 @default.
- W4287965010 cites W2966130489 @default.
- W4287965010 cites W2985315344 @default.
- W4287965010 cites W2986339307 @default.
- W4287965010 cites W3092042382 @default.
- W4287965010 cites W4238991969 @default.
- W4287965010 doi "https://doi.org/10.1039/d2sm00697a" @default.
- W4287965010 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35880460" @default.
- W4287965010 hasPublicationYear "2022" @default.
- W4287965010 type Work @default.
- W4287965010 citedByCount "4" @default.
- W4287965010 countsByYear W42879650102023 @default.
- W4287965010 crossrefType "journal-article" @default.
- W4287965010 hasAuthorship W4287965010A5036235720 @default.
- W4287965010 hasAuthorship W4287965010A5078767077 @default.
- W4287965010 hasBestOaLocation W42879650101 @default.
- W4287965010 hasConcept C104663316 @default.
- W4287965010 hasConcept C111337013 @default.
- W4287965010 hasConcept C111368507 @default.
- W4287965010 hasConcept C121332964 @default.
- W4287965010 hasConcept C127313418 @default.
- W4287965010 hasConcept C127413603 @default.
- W4287965010 hasConcept C155672457 @default.
- W4287965010 hasConcept C159985019 @default.
- W4287965010 hasConcept C171250308 @default.
- W4287965010 hasConcept C185544564 @default.
- W4287965010 hasConcept C192562407 @default.
- W4287965010 hasConcept C2778123984 @default.
- W4287965010 hasConcept C2778150588 @default.
- W4287965010 hasConcept C2778517922 @default.
- W4287965010 hasConcept C42360764 @default.
- W4287965010 hasConcept C49040817 @default.
- W4287965010 hasConcept C521977710 @default.
- W4287965010 hasConcept C53105671 @default.
- W4287965010 hasConcept C9271920 @default.
- W4287965010 hasConceptScore W4287965010C104663316 @default.
- W4287965010 hasConceptScore W4287965010C111337013 @default.
- W4287965010 hasConceptScore W4287965010C111368507 @default.
- W4287965010 hasConceptScore W4287965010C121332964 @default.
- W4287965010 hasConceptScore W4287965010C127313418 @default.
- W4287965010 hasConceptScore W4287965010C127413603 @default.
- W4287965010 hasConceptScore W4287965010C155672457 @default.
- W4287965010 hasConceptScore W4287965010C159985019 @default.
- W4287965010 hasConceptScore W4287965010C171250308 @default.
- W4287965010 hasConceptScore W4287965010C185544564 @default.
- W4287965010 hasConceptScore W4287965010C192562407 @default.
- W4287965010 hasConceptScore W4287965010C2778123984 @default.
- W4287965010 hasConceptScore W4287965010C2778150588 @default.