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- W4288037586 abstract "Abstract The Candida antarctica lipase B (Novozym 435) is found to catalyze a novel decarboxylative Michael addition in vinylogous carbamate systems for the synthesis of 1,4-benzoxazinone derivatives. The reaction goes through Michael addition, ester hydrolysis and decarboxylation. A possible mechanism is suggested, with simultaneous lipase-catalyzed Michael addition and ester hydrolysis. The present methodology offers formation of complex products through multi-step reactions in a one pot process under mild and facile reaction conditions with moderate to high yields (51–90%) and no side product formation. The reaction seems to be is a great example of enzymatic promiscuity." @default.
- W4288037586 created "2022-07-27" @default.
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- W4288037586 date "2022-07-26" @default.
- W4288037586 modified "2023-10-14" @default.
- W4288037586 title "Biocatalytic decarboxylative Michael addition for synthesis of 1,4-benzoxazinone derivatives" @default.
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- W4288037586 doi "https://doi.org/10.1038/s41598-022-16291-3" @default.
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