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- W4288045241 endingPage "154375" @default.
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- W4288045241 abstract "The dissolving of soluble lithium polysulfides (LiPSs) in electrolytes severely hinders the practical applications of Li-S batteries, anchoring material (AM) as a cathode additive restrains the dissolution of LiPSs. The -O/-S/-Se functionalized M2C (M = Ti, V, Cr, Mn) MXenes were comparative studied as AMs by first-principles calculations. We have studied the relationship between the anchoring effect and the valence electrons’ number (Ne) of metal elements in MXenes. Oxygen functional group MXene has drawbacks such as too strong interaction or semiconductor conductivity. However, for sulfur and selenium functional group M2C (M = V, Cr, Mn) MXenes, the moderate interaction of LiPSs and MXenes makes them suitable as AMs. For Ti-based MXene, Ti2CS2 and Ti2CSe2 have better electrical conductivity than Ti2CO2." @default.
- W4288045241 created "2022-07-27" @default.
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- W4288045241 date "2022-11-01" @default.
- W4288045241 modified "2023-10-06" @default.
- W4288045241 title "Functionalized M2CT2 (M = Ti, V, Cr, Mn; T = O, S, Se) MXenes as anchoring materials for lithium-sulfur batteries" @default.
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- W4288045241 doi "https://doi.org/10.1016/j.apsusc.2022.154375" @default.
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