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• W4288045404 endingPage "111740" @default.
• W4288045404 startingPage "111740" @default.
• W4288045404 abstract "Esters of 3-monochloropropane-1,2-diol (3-MCPD) and glycidol are reported vegetable fats and oils contaminants formed during processing. During digestion, esterified forms are hydrolyzed making the free forms, with high toxicity to human health, possibly available in the digestive system, which could depend, among other factors, on the phase condition stablished in the gastrointestinal tract between contaminants and lipids. Therefore, this work was aimed at evaluating the solid–liquid equilibrium (SLE) of binary and pseudobinary mixtures of fatty acids (palmitic, oleic and stearic), triacylglycerols (tripalmitin, triolein and tristearin) and a partial acylglycerols, with 3-MCPD and glycidol, by differential scanning calorimetry (DSC) and thermodynamic modeling with Margules 2 and 3 suffixes, UNIFAC and ideal models. Melting properties of the contaminants were determined by DSC thermograms, with microstructure micrographs and compared to some predictive group contribution models (GC). 14 complete SLE phase diagrams could be determined. Results showed that the lipid compounds had high affinity with the free contaminants with probably the formation of liquid crystalline structures and/or solid solutions. The Margules 3 suffixes model showed the best fit with the lowest average relative deviations, no higher than 1%, although the parameters probably incorporated the non-ideality promoted by the crystalline phase behavior. The formation of mesophases and/or solid solutions with very high melting temperature probably means a difficulty of separating the contaminants from the lipid matrix in which, on the other hand, could avoid separation process or affect (probably decreasing) their absorption during digestion." @default.
• W4288045404 created "2022-07-27" @default.
• W4288045404 creator A5003405122 @default.
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• W4288045404 date "2022-10-01" @default.
• W4288045404 modified "2023-10-15" @default.
• W4288045404 title "Solid-liquid equilibrium of free form of oil contaminants (3-MCPD and glycidol) in lipidic systems" @default.
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• W4288045404 doi "https://doi.org/10.1016/j.foodres.2022.111740" @default.
• W4288045404 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36076422" @default.
• W4288045404 hasPublicationYear "2022" @default.
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