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• W4288045779 endingPage "100914" @default.
• W4288045779 startingPage "100914" @default.
• W4288045779 abstract "Neodymium-based metal-organic framework (Nd-MOF) has been prepared as an efficient heterogeneous catalyst in the click synthesis of benzylidine-2-phenylhydrazine analogs for the first time. In the presence of Nd-MOF, the reaction proceeds with mild conditions and a comparable yield has been achieved with less reaction time. In order to synthesize the [Nd(NDC)1.5(DMF)(H2O)0.5.0.5DMF]n, neodymium is used as a metal node to act as a cation and naphthalene-2,6-dicarboxylic acid as a well-extended organic linker as a dicarboxylate anion for building good coordinated 3D polymer. The synthesized Nd-MOF nanocatalyst was characterized by Powder XRD, BET, TGA, FT-IR, SEM-EDX, and TEM. Finally, the obtained products were examined through 1H NMR, 13C NMR, 15N NMR and FT-IR. The nanocatalyst was completely recyclable and reusable for ten cycles without any loss of catalytic efficiency. Further, the nanocatalyst shows a crucial role in reducing the reaction time under mild experimental conditions. Additionally, the target molecules were afforded simple handling, eco-friendly and excellent yields with maximum efficiency." @default.
• W4288045779 created "2022-07-27" @default.
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• W4288045779 date "2022-10-01" @default.
• W4288045779 modified "2023-10-18" @default.
• W4288045779 title "Neodymium-based metal-organic framework as an efficient catalyst for green synthesis of benzylidene-2-phenylhydrazine analogues" @default.
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• W4288045779 doi "https://doi.org/10.1016/j.cdc.2022.100914" @default.
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