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- W4288439449 abstract "Abstract A synthetic route for the production of chiral derivatives of benzimidazole is presented. Different commercially available amines are evaluated as organocatalysts for the stereoselective aldol addition of N1-benzimidazolyl acetaldehyde, previously prepared by N-alkylation of benzimidazole, with cyclic ketones. When cyclohexanone was used, l-prolinamide proved to be the most efficient catalyst, giving (S)-2-((R)-2-(1H-benzo[d]imidazol-1-yl)-1-hydroxyethyl)cyclohexanone in 92% yield, 90% ee and 92:8 dr (anti/syn)." @default.
- W4288439449 created "2022-07-29" @default.
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- W4288439449 date "2022-07-28" @default.
- W4288439449 modified "2023-09-27" @default.
- W4288439449 title "Organocatalytic Synthesis of Benzimidazole Derivatives" @default.
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- W4288439449 doi "https://doi.org/10.1055/a-1911-6793" @default.
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