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• W4288441799 abstract "Palladium-catalyzed para-C-H bond amination of 2-aryl chloromethylbenzenes is described for the first time. The reactions of 2-aryl chloromethylbenzenes with cyclic amines proceeded smoothly in the presence of Pd(acac)2, tri(2-furyl)phosphine, and NaH in tetrahydrofuran at 40 °C to provide para-C-H bond aminated products in satisfactory to high yields with acceptable regioselectivity in most cases. The electronic property of the substituents linked to the benzene rings did not significantly influence the reactivity of the 2-aryl chloromethylbenzene substrates and the reaction regioselectivity." @default.
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• W4288441799 date "2022-07-28" @default.
• W4288441799 modified "2023-10-16" @default.
• W4288441799 title "Palladium-Catalyzed <i>Para</i>-C–H Bond Amination of 2-Aryl Chloromethylbenzenes" @default.
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• W4288441799 doi "https://doi.org/10.1021/acs.joc.2c01233" @default.
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