FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4288741560> ?p ?o ?g. }

• W4288741560 endingPage "118923" @default.
• W4288741560 startingPage "118923" @default.
• W4288741560 abstract "Broad molecular classification based on stoichiometric ratio relationships has been used extensively to characterize the chemical diversity of aquatic dissolved organic matter (DOM). However, variability in the molecular composition within this classification has remained elusive, thus limiting the interpretation of DOM dynamics, especially with respect to transport versus transformation patterns in response to hydrologic or landscape changes. Here, leveraging high-frequency spatiotemporal sampling during rainfall events at a Critical Zone Observatory project site in Clear Creek, Iowa, we apply a metabolomics-based analysis validated with fragmentation using tandem mass spectrometry to uncover patterns in the molecular features of the DOM composition that were not resolved by classification based on stoichiometric ratios in the chemical formulae. From upstream to downstream sites, beyond the increased aromaticity implied by changes in the stoichiometric ratios, we identified an increased abundance of flavonoids and other phenylpropanoids, two important subgroups of aromatic compounds. The stoichiometric analysis also proposed a localized decline in the abundance of lipid-like compounds, which we attributed specifically to medium-chain and short-chain fatty acids; other lipids such as long-chain fatty acids and sterol lipids remained unchanged. We further determined in-stream molecular transitions and specific compound degradation by capturing changes in the molecular masses of terpenoids, phenylpropanoids, fatty acids, and amino acids. In sum, the metabolomics analysis of the chemical formulae resolved molecular variability imprinted on the stoichiometric DOM composition to implicate key molecular subgroups underlying carbon transport and cycling dynamics in the stream." @default.
• W4288741560 created "2022-07-30" @default.
• W4288741560 creator A5030401347 @default.
• W4288741560 creator A5056102271 @default.
• W4288741560 creator A5074670714 @default.
• W4288741560 date "2022-09-01" @default.
• W4288741560 modified "2023-10-14" @default.
• W4288741560 title "Metabolomics analysis of unresolved molecular variability in stoichiometry dynamics of a stream dissolved organic matter" @default.
• W4288741560 cites W143096088 @default.
• W4288741560 cites W1893034613 @default.
• W4288741560 cites W1942549508 @default.
• W4288741560 cites W1964010911 @default.
• W4288741560 cites W1985030578 @default.
• W4288741560 cites W1990182562 @default.
• W4288741560 cites W2005742515 @default.
• W4288741560 cites W2010181898 @default.
• W4288741560 cites W2011126002 @default.
• W4288741560 cites W2028773871 @default.
• W4288741560 cites W2053708596 @default.
• W4288741560 cites W2054220331 @default.
• W4288741560 cites W2054491157 @default.
• W4288741560 cites W2060792463 @default.
• W4288741560 cites W2074226926 @default.
• W4288741560 cites W2083019709 @default.
• W4288741560 cites W2084375915 @default.
• W4288741560 cites W2085076764 @default.
• W4288741560 cites W2104583798 @default.
• W4288741560 cites W2116544104 @default.
• W4288741560 cites W2118855982 @default.
• W4288741560 cites W2123373395 @default.
• W4288741560 cites W2139050463 @default.
• W4288741560 cites W2162889508 @default.
• W4288741560 cites W2163312637 @default.
• W4288741560 cites W2168373789 @default.
• W4288741560 cites W2168590651 @default.
• W4288741560 cites W2188629597 @default.
• W4288741560 cites W2211459200 @default.
• W4288741560 cites W2313166464 @default.
• W4288741560 cites W2357545597 @default.
• W4288741560 cites W2388899390 @default.
• W4288741560 cites W2395814486 @default.
• W4288741560 cites W2522423596 @default.
• W4288741560 cites W2523469786 @default.
• W4288741560 cites W2634594562 @default.
• W4288741560 cites W2691860073 @default.
• W4288741560 cites W2737158998 @default.
• W4288741560 cites W2738498218 @default.
• W4288741560 cites W2789971498 @default.
• W4288741560 cites W2799896114 @default.
• W4288741560 cites W2800761186 @default.
• W4288741560 cites W2806651288 @default.
• W4288741560 cites W2911961078 @default.
• W4288741560 cites W2929263296 @default.
• W4288741560 cites W2938660733 @default.
• W4288741560 cites W2965140021 @default.
• W4288741560 cites W2965588545 @default.
• W4288741560 cites W2981088070 @default.
• W4288741560 cites W2987218928 @default.
• W4288741560 cites W2988557219 @default.
• W4288741560 cites W2990574920 @default.
• W4288741560 cites W2996424560 @default.
• W4288741560 cites W3092107817 @default.
• W4288741560 cites W3096596534 @default.
• W4288741560 cites W3097722657 @default.
• W4288741560 cites W3104636257 @default.
• W4288741560 cites W3110976553 @default.
• W4288741560 cites W3128951103 @default.
• W4288741560 cites W571098310 @default.
• W4288741560 doi "https://doi.org/10.1016/j.watres.2022.118923" @default.
• W4288741560 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36001905" @default.
• W4288741560 hasPublicationYear "2022" @default.
• W4288741560 type Work @default.
• W4288741560 citedByCount "4" @default.
• W4288741560 countsByYear W42887415602023 @default.
• W4288741560 crossrefType "journal-article" @default.
• W4288741560 hasAuthorship W4288741560A5030401347 @default.
• W4288741560 hasAuthorship W4288741560A5056102271 @default.
• W4288741560 hasAuthorship W4288741560A5074670714 @default.
• W4288741560 hasBestOaLocation W42887415601 @default.
• W4288741560 hasConcept C107872376 @default.
• W4288741560 hasConcept C147597530 @default.
• W4288741560 hasConcept C185592680 @default.
• W4288741560 hasConcept C21565614 @default.
• W4288741560 hasConcept C36574619 @default.
• W4288741560 hasConcept C43617362 @default.
• W4288741560 hasConcept C59593255 @default.
• W4288741560 hasConceptScore W4288741560C107872376 @default.
• W4288741560 hasConceptScore W4288741560C147597530 @default.
• W4288741560 hasConceptScore W4288741560C185592680 @default.
• W4288741560 hasConceptScore W4288741560C21565614 @default.
• W4288741560 hasConceptScore W4288741560C36574619 @default.
• W4288741560 hasConceptScore W4288741560C43617362 @default.
• W4288741560 hasConceptScore W4288741560C59593255 @default.
• W4288741560 hasFunder F4320306076 @default.
• W4288741560 hasFunder F4320309475 @default.
• W4288741560 hasLocation W42887415601 @default.
• W4288741560 hasLocation W42887415602 @default.
• W4288741560 hasOpenAccess W4288741560 @default.

• next