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- W4288857895 abstract "Nanomanipulation of molecular materials such as carbon nanotubes (CNTs) or new covalent organic frameworks (COFs) is key not only for the study of their fundamental physicochemical properties, but also for building and probing nanodevices. Therefore, we have investigated the tribological properties of oxidized MWCNTs (ox-MWCNTs) and their hybridization with COF building blocks ([email protected]) adsorbed on a mica surface. We used the AFM tip to apply torsional forces on individual nanotubes. Depending on the manipulation parameters, the lateral displacements of the AFM tip slide and/or bend nanotubes enabling the direct quantification of the nanotube-mica adhesion. We found striking changes in the behaviour of the lateral force needed to manipulate each carbon nanotube variant which indicates an increased adhesion of [email protected] with respect to ox-MWCNTs (∼10x). In addition, the use of the AFM tip as a mobile electrode enabled the measurement of electrical transport through individual nanotubes that revealed a rectifying behaviour of the [email protected] with high resistivity, which was in contrast with the near ohmic performance of ox-MWCNTs." @default.
- W4288857895 created "2022-07-30" @default.
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- W4288857895 date "2022-10-01" @default.
- W4288857895 modified "2023-10-18" @default.
- W4288857895 title "Nanotribology and electrical properties of carbon nanotubes hybridized with covalent organic frameworks" @default.
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- W4288857895 doi "https://doi.org/10.1016/j.carbon.2022.07.053" @default.
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