FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4289204855> ?p ?o ?g. }

• W4289204855 endingPage "M1416" @default.
• W4289204855 startingPage "M1416" @default.
• W4289204855 abstract "The synthesis and XRD characterization at 295 K of three isomers, X-fluoro-N-(2-hydroxy-5-methyl phenyl) benzamide: (o-FPhB), (m-FPhB), and (p-FPhB), are presented. o-FPhB and m-FPhB show high structural affinity concerning molecular and packing structures. The planarity of the C1-C7(O1)-N1-C8 peptide bond in o-FPhB, and m-FPhB confers high stability, favoring its tendency to acquire a resonant structure in the peptide segment and in the molecule. For p-FPhB, a stereochemical gate opens, leading to the activation of N-H∙∙∙∙O interpeptide bonds, defining its supramolecular properties. Active participation of the halogen in the assembly of the structures is observed, forming intramolecular rings and molecule chains during crystal growth. The o-FPhB and m-FPhB form parallel sheets that develop hydrogen C-H···Cg, halogen C-F···Cg, or C=O···Cg interactions. Theoretical evaluations of the properties performed by the DFT/B3LYP/(6-311G(d,p) showed good agreement with the experimental values. The IR analysis reaffirms the presence of N-H, C=O, O-H, C-F, and C-H. In the UV-Vis, an increase in the energetic stability, O···H interactions, and electrostatic potential in the NH region reaffirm the disposition of p-FPhB for the formation of the N-H···O interpeptide bond. A molecular docking on the benzamides involving protein receptors showed similar behavior for all three isomers." @default.
• W4289204855 created "2022-08-01" @default.
• W4289204855 creator A5032497571 @default.
• W4289204855 creator A5041199149 @default.
• W4289204855 creator A5044948891 @default.
• W4289204855 creator A5049430194 @default.
• W4289204855 creator A5091169774 @default.
• W4289204855 date "2022-07-29" @default.
• W4289204855 modified "2023-09-25" @default.
• W4289204855 title "Activation–Deactivation of Inter-Peptide Bond in Fluoro-N-(2-hydroxy-5-methyl phenyl)benzamide Isomers, Induced by the Position of the Halogen Atom in the Benzene Ring" @default.
• W4289204855 cites W121074824 @default.
• W4289204855 cites W1974534243 @default.
• W4289204855 cites W1990170643 @default.
• W4289204855 cites W1992582121 @default.
• W4289204855 cites W2012488984 @default.
• W4289204855 cites W2021720051 @default.
• W4289204855 cites W2023271753 @default.
• W4289204855 cites W2037131807 @default.
• W4289204855 cites W2043050545 @default.
• W4289204855 cites W2046001773 @default.
• W4289204855 cites W2074473216 @default.
• W4289204855 cites W2074529158 @default.
• W4289204855 cites W2077796804 @default.
• W4289204855 cites W2085442232 @default.
• W4289204855 cites W2086957099 @default.
• W4289204855 cites W2088702507 @default.
• W4289204855 cites W2105668062 @default.
• W4289204855 cites W2116480660 @default.
• W4289204855 cites W2128708905 @default.
• W4289204855 cites W2132525235 @default.
• W4289204855 cites W2132629607 @default.
• W4289204855 cites W2134967712 @default.
• W4289204855 cites W2146466816 @default.
• W4289204855 cites W2159065552 @default.
• W4289204855 cites W2227358287 @default.
• W4289204855 cites W2266334020 @default.
• W4289204855 cites W2411087330 @default.
• W4289204855 cites W2915626956 @default.
• W4289204855 cites W2978180062 @default.
• W4289204855 cites W3057402443 @default.
• W4289204855 cites W99290211 @default.
• W4289204855 doi "https://doi.org/10.3390/m1416" @default.
• W4289204855 hasPublicationYear "2022" @default.
• W4289204855 type Work @default.
• W4289204855 citedByCount "0" @default.
• W4289204855 crossrefType "journal-article" @default.
• W4289204855 hasAuthorship W4289204855A5032497571 @default.
• W4289204855 hasAuthorship W4289204855A5041199149 @default.
• W4289204855 hasAuthorship W4289204855A5044948891 @default.
• W4289204855 hasAuthorship W4289204855A5049430194 @default.
• W4289204855 hasAuthorship W4289204855A5091169774 @default.
• W4289204855 hasBestOaLocation W42892048551 @default.
• W4289204855 hasConcept C112887158 @default.
• W4289204855 hasConcept C115624301 @default.
• W4289204855 hasConcept C178790620 @default.
• W4289204855 hasConcept C185592680 @default.
• W4289204855 hasConcept C23029723 @default.
• W4289204855 hasConcept C2779281246 @default.
• W4289204855 hasConcept C2780231548 @default.
• W4289204855 hasConcept C2780378348 @default.
• W4289204855 hasConcept C32909587 @default.
• W4289204855 hasConcept C55493867 @default.
• W4289204855 hasConcept C71240020 @default.
• W4289204855 hasConcept C75079739 @default.
• W4289204855 hasConcept C8010536 @default.
• W4289204855 hasConcept C93275456 @default.
• W4289204855 hasConceptScore W4289204855C112887158 @default.
• W4289204855 hasConceptScore W4289204855C115624301 @default.
• W4289204855 hasConceptScore W4289204855C178790620 @default.
• W4289204855 hasConceptScore W4289204855C185592680 @default.
• W4289204855 hasConceptScore W4289204855C23029723 @default.
• W4289204855 hasConceptScore W4289204855C2779281246 @default.
• W4289204855 hasConceptScore W4289204855C2780231548 @default.
• W4289204855 hasConceptScore W4289204855C2780378348 @default.
• W4289204855 hasConceptScore W4289204855C32909587 @default.
• W4289204855 hasConceptScore W4289204855C55493867 @default.
• W4289204855 hasConceptScore W4289204855C71240020 @default.
• W4289204855 hasConceptScore W4289204855C75079739 @default.
• W4289204855 hasConceptScore W4289204855C8010536 @default.
• W4289204855 hasConceptScore W4289204855C93275456 @default.
• W4289204855 hasIssue "3" @default.
• W4289204855 hasLocation W42892048551 @default.
• W4289204855 hasLocation W42892048552 @default.
• W4289204855 hasOpenAccess W4289204855 @default.
• W4289204855 hasPrimaryLocation W42892048551 @default.
• W4289204855 hasRelatedWork W2012675768 @default.
• W4289204855 hasRelatedWork W2034230510 @default.
• W4289204855 hasRelatedWork W2092928577 @default.
• W4289204855 hasRelatedWork W2320657324 @default.
• W4289204855 hasRelatedWork W2345332579 @default.
• W4289204855 hasRelatedWork W2504212939 @default.
• W4289204855 hasRelatedWork W2526066714 @default.
• W4289204855 hasRelatedWork W2788975530 @default.
• W4289204855 hasRelatedWork W2790799920 @default.
• W4289204855 hasRelatedWork W583820436 @default.
• W4289204855 hasVolume "2022" @default.
• W4289204855 isParatext "false" @default.
• W4289204855 isRetracted "false" @default.

• next