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• W4289277594 abstract "The Ca 2+ -doped LaVO 4 :Eu 3+ nanocrystals were synthesized via a simple solvothermal route. The phase, morphology, as well as optical property were studied detailedly. The experimental results demonstrated that Ca 2+ ions restricted the further growth of LaVO 4 :Eu 3+ nanocrystals and raised the photoluminescence (PL) intensity concurrently. The formation mechanism and fluorescent property variation were systematically investigated. Because of the charge mismatch, the Cu 2+ ions were attracted onto the grain surface by negative poles generated in the doping process. Then energy transfer (ET) occurred from Eu 3+ to Cu 2+ , which caused the fluorescence quenching. Remarkably, the limit of detection for Cu 2+ ions was as low as 0.492 μM. Hence, it would be served as a sensitive fluorescent probe for Cu 2+ ions detection. • The Ca 2+ -doped LaVO 4 :Eu 3+ nanomaterials are fabricated via a solvothermal route. • Energy transfer occurs from Eu 3+ to Cu 2+ after Cu 2+ ion adsorption. • A possible energy transfer mechanism is given to explain the fluorescence quenching. • The nanomaterials may have potential applications in Cu 2+ ion detection." @default.
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• W4289277594 date "2022-10-01" @default.
• W4289277594 modified "2023-10-16" @default.
• W4289277594 title "Fluorescent Ca2+-doped LaVO4:Eu3+ nanocrystals featuring highly sensitive detecting Cu2+ ions" @default.
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• W4289277594 doi "https://doi.org/10.1016/j.optmat.2022.112766" @default.
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