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- W4289277610 abstract "The core H2/CO/NOx mechanism is important in understanding the mechanism of NOx formation during combustion as it forms the base model in developing kinetic models of larger hydrocarbons/NOx systems. Recently, the Goldsmith group at Brown University performed high-level ab-initio calculations of the chemistry of HONO and HNO2 and proposed that the thermal rate constant of isomerization of HONO to HNO2 is orders of magnitude lower than that used in all previous models. This discrepancy may lead to a deviation in understanding the formation mechanism of NOx. With this in mind, coupling with the latest rate constants obtained by experimental measurements and high-level quantum chemistry calculations, the H2/CO/NOx model was circularly updated and re-verified against multi-type datasets over a wide range of initial conditions and experimental devices. The proposed model (XJTUNO-2021) can accurately reproduce almost all of the fundamental combustion data including 156 shock tube datasets, 87 JSR datasets, 114 flow reactor datasets and six laminar flame speed datasets in the literature from 1959 to 2021. Moreover, this study clarifies the shortcomings of the Zhang mechanism of CO/NOx systems. Finally, the updated model has been used to simulate the formation of NO at practical gas-turbine conditions to give more kinetically information of NO control technologies." @default.
- W4289277610 created "2022-08-01" @default.
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- W4289277610 date "2022-11-01" @default.
- W4289277610 modified "2023-10-16" @default.
- W4289277610 title "Further insights into the core mechanism of H2/CO/NOx reaction system" @default.
- W4289277610 cites W1498036415 @default.
- W4289277610 cites W1862964234 @default.
- W4289277610 cites W1918750314 @default.
- W4289277610 cites W1920158078 @default.
- W4289277610 cites W196092558 @default.
- W4289277610 cites W1963632609 @default.
- W4289277610 cites W1963679491 @default.
- W4289277610 cites W1974821556 @default.
- W4289277610 cites W1977513091 @default.
- W4289277610 cites W1978784824 @default.
- W4289277610 cites W1979958120 @default.
- W4289277610 cites W1982742040 @default.
- W4289277610 cites W1983701766 @default.
- W4289277610 cites W1986235120 @default.
- W4289277610 cites W1988004523 @default.
- W4289277610 cites W1988091937 @default.
- W4289277610 cites W1990072613 @default.
- W4289277610 cites W1993077801 @default.
- W4289277610 cites W1993751147 @default.
- W4289277610 cites W1996318704 @default.
- W4289277610 cites W1996376905 @default.
- W4289277610 cites W2011581530 @default.
- W4289277610 cites W2015733877 @default.
- W4289277610 cites W2017907573 @default.
- W4289277610 cites W2018570951 @default.
- W4289277610 cites W2021904240 @default.
- W4289277610 cites W2034166514 @default.
- W4289277610 cites W2036677794 @default.
- W4289277610 cites W2040805965 @default.
- W4289277610 cites W2042321058 @default.
- W4289277610 cites W2047269263 @default.
- W4289277610 cites W2047285617 @default.
- W4289277610 cites W2059818465 @default.
- W4289277610 cites W2061827065 @default.
- W4289277610 cites W2068364642 @default.
- W4289277610 cites W2069006374 @default.
- W4289277610 cites W2069338627 @default.
- W4289277610 cites W2070967523 @default.
- W4289277610 cites W2074126556 @default.
- W4289277610 cites W2074294458 @default.
- W4289277610 cites W2076892997 @default.
- W4289277610 cites W2082794077 @default.
- W4289277610 cites W2090067667 @default.
- W4289277610 cites W2114231613 @default.
- W4289277610 cites W2119704402 @default.
- W4289277610 cites W2137910740 @default.
- W4289277610 cites W2142893770 @default.
- W4289277610 cites W2150697053 @default.
- W4289277610 cites W2160374836 @default.
- W4289277610 cites W2345380035 @default.
- W4289277610 cites W2513614203 @default.
- W4289277610 cites W2516544451 @default.
- W4289277610 cites W2611598360 @default.
- W4289277610 cites W2724612357 @default.
- W4289277610 cites W2749793678 @default.
- W4289277610 cites W2766692944 @default.
- W4289277610 cites W2790320648 @default.
- W4289277610 cites W2810966780 @default.
- W4289277610 cites W2886809878 @default.
- W4289277610 cites W2888794417 @default.
- W4289277610 cites W2891471555 @default.
- W4289277610 cites W2891965824 @default.
- W4289277610 cites W2902755028 @default.
- W4289277610 cites W2913204900 @default.
- W4289277610 cites W2914858083 @default.
- W4289277610 cites W2945029084 @default.
- W4289277610 cites W2993503996 @default.
- W4289277610 cites W2996293278 @default.
- W4289277610 cites W2996436222 @default.
- W4289277610 cites W3034163439 @default.
- W4289277610 cites W3038110760 @default.
- W4289277610 cites W3046725413 @default.
- W4289277610 cites W3083482543 @default.
- W4289277610 cites W3084468717 @default.
- W4289277610 cites W3087881171 @default.
- W4289277610 cites W3092985421 @default.
- W4289277610 cites W3094616451 @default.
- W4289277610 cites W3095823813 @default.
- W4289277610 cites W3111620093 @default.
- W4289277610 cites W3122350664 @default.
- W4289277610 cites W4244907949 @default.