Matches in SemOpenAlex for { <https://semopenalex.org/work/W4289308100> ?p ?o ?g. }
- W4289308100 abstract "Abstract (3+2) cycloaddition reactions are undeniably one of the most robust and versatile synthetic tools in heterocyclic chemistry. The classically required 1,3‐dipoles are however limited to three‐atom sequences bearing stabilized formal charges in their Lewis structure. The scope of three‐atom groupings possible in (3+2) cycloadditions can be greatly expanded by taking of advantage neutral three‐atom components (TACs). These groupings result in zwitterionic (3+2) cycloadducts adaptable to multiple outcomes depending on structure and conditions. Herein, the intramolecular (3+2) cycloaddition reaction between alkynyl sulfides (neutral TAC) and alkynes to provide key thiophenium ylide intermediates is first reported. These reactive species provide access to highly substituted fused thiophenes following predictable chemical sequences. Structural features on the obtained thiophenes were highly configurable by judicious choice of both alkynyl sulfide substitution and reaction conditions." @default.
- W4289308100 created "2022-08-02" @default.
- W4289308100 creator A5024528559 @default.
- W4289308100 creator A5044126833 @default.
- W4289308100 creator A5076670951 @default.
- W4289308100 date "2022-06-24" @default.
- W4289308100 modified "2023-10-10" @default.
- W4289308100 title "The Synthetic Potential of Thiophenium Ylide Cycloadducts**" @default.
- W4289308100 cites W1975462243 @default.
- W4289308100 cites W1987125791 @default.
- W4289308100 cites W1988604663 @default.
- W4289308100 cites W1992546202 @default.
- W4289308100 cites W2004330407 @default.
- W4289308100 cites W2041959429 @default.
- W4289308100 cites W2052583141 @default.
- W4289308100 cites W2084161203 @default.
- W4289308100 cites W2098624753 @default.
- W4289308100 cites W2100082893 @default.
- W4289308100 cites W2133163790 @default.
- W4289308100 cites W2137577190 @default.
- W4289308100 cites W2141161706 @default.
- W4289308100 cites W2145093709 @default.
- W4289308100 cites W2165340338 @default.
- W4289308100 cites W2170863911 @default.
- W4289308100 cites W2171660150 @default.
- W4289308100 cites W2296967601 @default.
- W4289308100 cites W2495755089 @default.
- W4289308100 cites W2519763229 @default.
- W4289308100 cites W2774639854 @default.
- W4289308100 cites W2888028391 @default.
- W4289308100 cites W2889308482 @default.
- W4289308100 cites W2949811628 @default.
- W4289308100 cites W2950434415 @default.
- W4289308100 cites W2952347161 @default.
- W4289308100 cites W2952374458 @default.
- W4289308100 cites W2952600348 @default.
- W4289308100 cites W2953312571 @default.
- W4289308100 cites W3014456571 @default.
- W4289308100 cites W3017332432 @default.
- W4289308100 cites W3034909043 @default.
- W4289308100 cites W3043189202 @default.
- W4289308100 cites W3048080960 @default.
- W4289308100 cites W3081631628 @default.
- W4289308100 cites W3083685729 @default.
- W4289308100 cites W3097706913 @default.
- W4289308100 cites W3139512242 @default.
- W4289308100 cites W3171331289 @default.
- W4289308100 cites W3188493353 @default.
- W4289308100 cites W4232677533 @default.
- W4289308100 doi "https://doi.org/10.1002/ange.202205963" @default.
- W4289308100 hasPublicationYear "2022" @default.
- W4289308100 type Work @default.
- W4289308100 citedByCount "1" @default.
- W4289308100 countsByYear W42893081002023 @default.
- W4289308100 crossrefType "journal-article" @default.
- W4289308100 hasAuthorship W4289308100A5024528559 @default.
- W4289308100 hasAuthorship W4289308100A5044126833 @default.
- W4289308100 hasAuthorship W4289308100A5076670951 @default.
- W4289308100 hasConcept C147597530 @default.
- W4289308100 hasConcept C149635348 @default.
- W4289308100 hasConcept C161790260 @default.
- W4289308100 hasConcept C163638829 @default.
- W4289308100 hasConcept C178790620 @default.
- W4289308100 hasConcept C185592680 @default.
- W4289308100 hasConcept C21951064 @default.
- W4289308100 hasConcept C2779167645 @default.
- W4289308100 hasConcept C2779664164 @default.
- W4289308100 hasConcept C2780596425 @default.
- W4289308100 hasConcept C41008148 @default.
- W4289308100 hasConcept C58312451 @default.
- W4289308100 hasConcept C71240020 @default.
- W4289308100 hasConcept C75079739 @default.
- W4289308100 hasConceptScore W4289308100C147597530 @default.
- W4289308100 hasConceptScore W4289308100C149635348 @default.
- W4289308100 hasConceptScore W4289308100C161790260 @default.
- W4289308100 hasConceptScore W4289308100C163638829 @default.
- W4289308100 hasConceptScore W4289308100C178790620 @default.
- W4289308100 hasConceptScore W4289308100C185592680 @default.
- W4289308100 hasConceptScore W4289308100C21951064 @default.
- W4289308100 hasConceptScore W4289308100C2779167645 @default.
- W4289308100 hasConceptScore W4289308100C2779664164 @default.
- W4289308100 hasConceptScore W4289308100C2780596425 @default.
- W4289308100 hasConceptScore W4289308100C41008148 @default.
- W4289308100 hasConceptScore W4289308100C58312451 @default.
- W4289308100 hasConceptScore W4289308100C71240020 @default.
- W4289308100 hasConceptScore W4289308100C75079739 @default.
- W4289308100 hasFunder F4320310630 @default.
- W4289308100 hasFunder F4320334593 @default.
- W4289308100 hasIssue "32" @default.
- W4289308100 hasLocation W42893081001 @default.
- W4289308100 hasOpenAccess W4289308100 @default.
- W4289308100 hasPrimaryLocation W42893081001 @default.
- W4289308100 hasRelatedWork W2010620744 @default.
- W4289308100 hasRelatedWork W2120747968 @default.
- W4289308100 hasRelatedWork W2124010857 @default.
- W4289308100 hasRelatedWork W2950401301 @default.
- W4289308100 hasRelatedWork W2950498759 @default.
- W4289308100 hasRelatedWork W2951188401 @default.
- W4289308100 hasRelatedWork W2952054667 @default.
- W4289308100 hasRelatedWork W2952615693 @default.