Matches in SemOpenAlex for { <https://semopenalex.org/work/W4289314097> ?p ?o ?g. }
- W4289314097 endingPage "845" @default.
- W4289314097 startingPage "845" @default.
- W4289314097 abstract "We examined the relationship between the intrinsic structure of a carbocatalyst and catalytic activity of peroxomonosulfate (PMS) activation for acetaminophen degradation. A series of nitrogen-doped carbon nanotubes with different degrees of oxidation was synthesized by the unzipping method. The linear regression analysis proposes that pyridinic N and graphitic N played a key role in the catalytic oxidation, rather than pyrrolic N and oxidized N. Pyridinic N reinforce the electron population in the graphitic framework and initiate the non-radical pathway via the formation of surface-bound radicals. Furthermore, graphitic N forms activated complexes (carbocatalyst-PMS*), facilitating the electron-transfer oxidative pathway. The correlation also affirms that -C=O was dominantly involved as a main active site, rather than -C-OH and -COOH. This study can be viewed as the first attempt to demonstrate the relationship between the fraction of N-groups and activity, and the quantity of O-groups and activity by active species (quenching studies) was established to reveal the role of N-groups and O-groups in the radical and non-radical pathways." @default.
- W4289314097 created "2022-08-02" @default.
- W4289314097 creator A5058665941 @default.
- W4289314097 creator A5063232807 @default.
- W4289314097 creator A5076926572 @default.
- W4289314097 date "2022-08-01" @default.
- W4289314097 modified "2023-10-16" @default.
- W4289314097 title "Role of N-Doping and O-Groups in Unzipped N-Doped CNT Carbocatalyst for Peroxomonosulfate Activation: Quantitative Structure–Activity Relationship" @default.
- W4289314097 cites W1525890247 @default.
- W4289314097 cites W1926950498 @default.
- W4289314097 cites W1961453377 @default.
- W4289314097 cites W1987952875 @default.
- W4289314097 cites W1991821581 @default.
- W4289314097 cites W1996906301 @default.
- W4289314097 cites W1997867411 @default.
- W4289314097 cites W2002775994 @default.
- W4289314097 cites W2010479638 @default.
- W4289314097 cites W2012998347 @default.
- W4289314097 cites W2017313611 @default.
- W4289314097 cites W2017339042 @default.
- W4289314097 cites W2025340493 @default.
- W4289314097 cites W2051611630 @default.
- W4289314097 cites W2055207887 @default.
- W4289314097 cites W2062954860 @default.
- W4289314097 cites W2068765991 @default.
- W4289314097 cites W2077639808 @default.
- W4289314097 cites W2080020076 @default.
- W4289314097 cites W2085028585 @default.
- W4289314097 cites W2095494712 @default.
- W4289314097 cites W2108978957 @default.
- W4289314097 cites W2110757989 @default.
- W4289314097 cites W2111088912 @default.
- W4289314097 cites W2111427861 @default.
- W4289314097 cites W2116900491 @default.
- W4289314097 cites W2119373472 @default.
- W4289314097 cites W2137737658 @default.
- W4289314097 cites W2141226455 @default.
- W4289314097 cites W2157719105 @default.
- W4289314097 cites W2169578870 @default.
- W4289314097 cites W2280351861 @default.
- W4289314097 cites W2328967289 @default.
- W4289314097 cites W2344036593 @default.
- W4289314097 cites W2344042588 @default.
- W4289314097 cites W2408898971 @default.
- W4289314097 cites W2495744501 @default.
- W4289314097 cites W2549427229 @default.
- W4289314097 cites W256457453 @default.
- W4289314097 cites W2571465304 @default.
- W4289314097 cites W2586783714 @default.
- W4289314097 cites W2617563720 @default.
- W4289314097 cites W2739613792 @default.
- W4289314097 cites W2752779042 @default.
- W4289314097 cites W2770092632 @default.
- W4289314097 cites W2770125280 @default.
- W4289314097 cites W2770231450 @default.
- W4289314097 cites W2770561121 @default.
- W4289314097 cites W2774601612 @default.
- W4289314097 cites W2790656902 @default.
- W4289314097 cites W2886392700 @default.
- W4289314097 cites W2899399883 @default.
- W4289314097 cites W2944518459 @default.
- W4289314097 cites W2950851730 @default.
- W4289314097 cites W2995688716 @default.
- W4289314097 cites W2996223098 @default.
- W4289314097 cites W2997469998 @default.
- W4289314097 cites W3004404113 @default.
- W4289314097 cites W3005806989 @default.
- W4289314097 cites W3008264207 @default.
- W4289314097 cites W3017101350 @default.
- W4289314097 cites W3022707741 @default.
- W4289314097 cites W3027057572 @default.
- W4289314097 cites W3034345321 @default.
- W4289314097 cites W3092395823 @default.
- W4289314097 cites W3096877206 @default.
- W4289314097 cites W3119044526 @default.
- W4289314097 cites W3133036236 @default.
- W4289314097 cites W3134151589 @default.
- W4289314097 cites W3139368641 @default.
- W4289314097 cites W3170639883 @default.
- W4289314097 cites W3174241132 @default.
- W4289314097 cites W3198852968 @default.
- W4289314097 cites W3207216731 @default.
- W4289314097 cites W4281983309 @default.
- W4289314097 doi "https://doi.org/10.3390/catal12080845" @default.
- W4289314097 hasPublicationYear "2022" @default.
- W4289314097 type Work @default.
- W4289314097 citedByCount "14" @default.
- W4289314097 countsByYear W42893140972022 @default.
- W4289314097 countsByYear W42893140972023 @default.
- W4289314097 crossrefType "journal-article" @default.
- W4289314097 hasAuthorship W4289314097A5058665941 @default.
- W4289314097 hasAuthorship W4289314097A5063232807 @default.
- W4289314097 hasAuthorship W4289314097A5076926572 @default.
- W4289314097 hasBestOaLocation W42893140971 @default.
- W4289314097 hasConcept C121332964 @default.
- W4289314097 hasConcept C121745418 @default.
- W4289314097 hasConcept C123669783 @default.
- W4289314097 hasConcept C139066938 @default.