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- W4289538426 abstract "In nuclear technology, zirconium dioxide and thorium dioxide take an essential role as fuel-based materials. It is necessary to understand the thermodynamics characteristics of those materials for waste treatment purposes. In this case, one of the characteristics that take focus is the dissolution rate. Both materials are polycrystalline, where zirconium dioxide has three phases: monoclinic, tetragonal, and cubic. Stabilized cubic zirconium dioxide is considered essential in the ongoing research of Inert Matrix Fuel (IMF). However, only a few studies report the dissolution rate in the cubic form; the values vary under various conditioned parameters. Due to its great work and research, thorium dioxide is used as sample material to fill in the gaps for zirconia. This idea is based on the similarities of their cubic crystalline structure and complex ions, especially the dominant tetrametric species on both materials. The method used is to compare each material, find the similarity, and eliminate the difference. The initial findings yielded a specific calculation using constant solubility product (Ksp) and the Gibbs energy (G) used to study the thermodynamics parameters of thorium dioxide. Hence, it is in our favor to analyze the measures and the relations to be applied with zirconium dioxide." @default.
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- W4289538426 date "2022-01-01" @default.
- W4289538426 modified "2023-10-18" @default.
- W4289538426 title "A review on the solubility of crystalline zirconium dioxide and thorium dioxide" @default.
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- W4289538426 doi "https://doi.org/10.1063/5.0093941" @default.
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