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- W4289596937 abstract "The poor stability of heterogenized nickel phthalocyanine (NiPc) has hindered its application as a desirable catalyst for electrocatalytic carbon dioxide reduction. Herein, the electrocatalytic stability of heterogenized NiPc on nitrogen-doped hollow carbon nanospheres ([email protected]) can be optimized via mediating NiPc into Ni-NC moiety (Ni-NC/NHCSs-Y) to construct a stable Ni catalytic unit. Different from the poor activity of [email protected] (CO Faradaic efficiency, FECO< 80%, stability < 1200 s), the optimal catalyst (Ni-NC/NHCSs-600) with unsaturated Ni-N3 nitrogen-vacancy structure, displays FECO of 98.57% and CO turnover frequency of 3.75 s−1 at − 0.87 V vs. RHE, and stable operation over 14 h (−0.82 V vs. RHE). The stabilization mechanism and the temperature effect on the structure-activity relationship are systematically explored, which successfully steers the design of stable Ni-NC catalytic unit on different carbon substrate, while a zinc-CO2 rechargeable battery is constructed, displaying a peak power density of 0.64 mW cm−2 and FECO of 91.45%." @default.
- W4289596937 created "2022-08-03" @default.
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- W4289596937 date "2022-12-01" @default.
- W4289596937 modified "2023-10-01" @default.
- W4289596937 title "Mediating heterogenized nickel phthalocyanine into isolated Ni-N3 moiety for improving activity and stability of electrocatalytic CO2 reduction" @default.
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- W4289596937 doi "https://doi.org/10.1016/j.apcatb.2022.121813" @default.
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