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- W4289779610 abstract "We herein describe a highly selective Rh(I)-catalyzed defluorinative coupling of boronic acids with (E)-β-monofluoroacrylates. In contrast to previous methods, the trisubstituted (Z)-alkene products were obtained in excellent dr with an inversion of double bond geometry. Experimental and computational studies established that Rh(I)-facilitated β-F elimination is favored over competing β-H elimination and protodemetalation." @default.
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- W4289779610 date "2022-08-04" @default.
- W4289779610 modified "2023-09-23" @default.
- W4289779610 title "Rhodium(I)-Catalyzed Defluorinative Coupling of Boronic Acids with Monofluoroalkenes" @default.
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- W4289779610 doi "https://doi.org/10.1021/acs.orglett.2c02294" @default.
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