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• W4290547237 abstract "An Si/Cu composite anode was prepared using a facile solid mechanosynthesis method and wet chemical etching. Phase transition and morphologies were investigated on pristine and as-synthesized composites. Effects of presence of Al 80 Si 20 and super p carbon on ball-milling were investigated. Moreover, the etching effect was compared with that of pristine Cu–Zn and composites by addition of NH 4 Cl. The results of X-ray diffraction patterns, scanning-electron-microscopy morphological images, and focus-ion-beam/energy-dispersive mapping demonstrated that the formation of the intermetallic, elemental distribution, homogeneity, and dezincification is involved with the addition of Al, super p carbon, and etching additive NH 4 Cl. Super p carbon avoided the formation of Cu–Si, while Al made the more homogenous distribution of Si/Cu. The two synthesized types of Si/Cu composites deliver specific capacity/retention rates of 608 mAhg −1 /66.4% (Si/Cu from pure Si) and 707 mAhg −1 /81.1% (Si/Cu from Al 80 Si 20 ) after 200 cycles, respectively. The higher stability of the galvanostatic cycling and capability performance resulted from the homogeneity of Si and Cu." @default.
• W4290547237 created "2022-08-08" @default.
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• W4290547237 date "2022-08-08" @default.
• W4290547237 modified "2023-10-18" @default.
• W4290547237 title "Si/Cu composite as anode material for lithium-ion batteries" @default.
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• W4290547237 doi "https://doi.org/10.3389/fenrg.2022.968259" @default.
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